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"一锅法"合成3-羟基丁酸乙酯的研究 被引量:1

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摘要 研究了以八羰基二钴为主催化剂,不同的含N、P化合物为助剂,环氧丙烷与CO、乙醇发生氢酯基化反应;并考察了不同的溶剂对反应的影响.结果表明,在所考察的助剂中以3-羟基吡啶的作用最为显著,当CO2(CO)8与3-羟基吡啶的摩尔比为1/3时,环氧丙烷的转化率可达96.2%,3-羟基丁酸乙酯的选择性为93.1%.并且对反应机理进行了探讨.
作者 刘建华 陈静
机构地区 中国科学院
出处 《石油化工》 CAS CSCD 北大核心 2004年第z1期413-415,共3页 Petrochemical Technology
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同被引文献23

  • 1宣磊,郑建永,何耀莹,汪钊.微生物酯酶催化合成(R)-3-羟基丁酸乙酯[J].发酵科技通讯,2013,42(2):13-17. 被引量:3
  • 2于明安,朱晓冰,祁巍,赵领,魏郁梦.CTAB透性化酵母细胞生物催化合成(S)-(+)-3-羟基丁酸乙酯[J].催化学报,2005,26(7):609-613. 被引量:11
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