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SINGLE LANTHANUM TRIS(N-PHENYLETHYL-3,5-DI-t-BUTYLSALICYLALDIMINATO)S INITIATOR FOR RING-OPENING POLYMERIZATION OF 1,4-DIOXAN-2-ONE IN BULK

SINGLE LANTHANUM TRIS(N-PHENYLETHYL-3,5-DI-t-BUTYLSALICYLALDIMINATO)S INITIATOR FOR RING-OPENING POLYMERIZATION OF 1,4-DIOXAN-2-ONE IN BULK
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摘要 A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-one (PDO) in bulk.The influence of reaction conditions,such as polymerization temperature,the molar ratio of the monomer to initiator (M/I) on the monomer conversion and molecular weight of the polymer has been investigated.Poly(1,4-dioxan-2-one) with a viscosity-average molecular weight (My) o... A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-one (PDO) in bulk.The influence of reaction conditions,such as polymerization temperature,the molar ratio of the monomer to initiator (M/I) on the monomer conversion and molecular weight of the polymer has been investigated.Poly(1,4-dioxan-2-one) with a viscosity-average molecular weight (My) o...
作者 郑豪 沈之荃
机构地区 Department of Chemistry Key Laboratory of Macromolecule Synthesis and Functionalization
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2008年第6期799-801,共3页 高分子科学（英文版）
基金 supported by the National Natural Science Foundation of China (Key program,Nos.G20434020 and G20774078).
关键词 1 4-Dioxan-2-one Ring-opening polymerization Lanthanum tris（N-phenylethyl-3 5-di-t-butylsalicylaldiminato）s. 1 4-Dioxan-2-one Ring-opening polymerization Lanthanum tris（N-phenylethyl-3 5-di-t-butylsalicylaldiminato）s.
分类号 O631.5 [理学—高分子化学]
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Chinese Journal of Polymer Science
2008年 第6期

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