摘要
２，２－ 二苯基六甲基三硅烷在三氯化铝的催化下，向反应体系中通入干燥的氯化氢时不是一步生成了２，２－二氯六甲基三硅烷，而是先生成了２－氯－２－苯基六甲基三硅烷，然后再转化得到预期的产物． 通过用制备色谱获得了中间产物以及气相色谱跟踪反应，较详细地观察了反应物转化的过程．
Dichlorohexamethyltrisilane can not be prepared from 2,2 diphenylhexa methyltrisilane and dry hydrogen chloride with catalytic aluminum chloride in one step; 2 Chloro 2 phenylhexamethyltrisilane was first obtained instead. The latter was transferred into 2,2 dichlorohexamethyltrisilane. 2 Chloro 2 phenylhexamethyltrisilane was prepared from the reaction solution with preparative Gas Chromatography, this reaction was monitored by Gas Chromatography. This paper reported the reaction route in detail.
出处
《上海师范大学学报（自然科学版）》
1999年第4期72-75,共4页
Journal of Shanghai Normal University(Natural Sciences)
基金
上海市教育委员会青年基金!(96QF46)
