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Open metallocenes——Ⅺ. A pentadienyl compound of heavier rare earth element [2,4-(CH_3)_2-η~5-C_5H_5]_3Tb·1/2THF

Open metallocenes——Ⅺ. A pentadienyl compound of heavier rare earth element [2,4-(CH_3)_2-η~5-C_5H_5]_3Tb·1/2THF
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摘要 Perfluoroalkyl iodides reacted with conjugated dienes in aqueous acetonitrile solution in the presence of sodium dithionite at room temperature to give dimerization products, whereas, perfluo- roalkanesulfonyl bromides reacted with conjugated dienes to form 1,4-adducts under actinic irradiation. Perfluoroalkyl iodides reacted with conjugated dienes in aqueous acetonitrile solution in the presence of sodium dithionite at room temperature to give dimerization products, whereas, perfluo- roalkanesulfonyl bromides reacted with conjugated dienes to form 1,4-adducts under actinic irradiation.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1991年第1期10-19,共0页 中国化学(英文版)
基金 This research was supported by the National Natural Science Foundation of China as an item of major project.
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