摘要
Perfluoroalkyl iodides reacted with conjugated dienes in aqueous acetonitrile solution in the presence of sodium dithionite at room temperature to give dimerization products, whereas, perfluo- roalkanesulfonyl bromides reacted with conjugated dienes to form 1,4-adducts under actinic irradiation.
Perfluoroalkyl iodides reacted with conjugated dienes in aqueous acetonitrile solution in the presence of sodium dithionite at room temperature to give dimerization products, whereas, perfluo- roalkanesulfonyl bromides reacted with conjugated dienes to form 1,4-adducts under actinic irradiation.
基金
This research was supported by the National Natural Science Foundation of China as an item of major project.