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介孔结构多酸掺杂-锐钛矿纳米晶Na_4W_(10)O_(32)/TiO_2的制备及其可见光光催化性能研究 被引量:5

Preparation and Visible-light Photocatalytic Properties of Polyoxometalate-doped Anatase Nanocrystal Na_4W_(10)O_(32)/TiO_2 with Mesoporous Structure
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摘要 A simple and rapid process has been developed for the preparation of mesoporous anatase TiO 2 crystalline particles coupled by homogeneously dispersed Na 4W 10 O 32 at a lower temperature ( 200 ℃ ) by combining sol-gel and programmed temperature hydrothermal methods. The composite,Na 4W 10 O 32 /TiO 2,has a uniform mesopore distribution with the average pore diameter of 3.8 nm,and its BET surface area is 178.4 m 2/g. The average size of the composite is below 10 nm. This new photocatalyst exhibited a visible-light photocatalytic activity to decompose para -thion-methyl. A simple and rapid process has been developed for the preparation of mesoporous anatase TiO 2 crystalline particles coupled by homogeneously dispersed Na 4W 10 O 32 at a lower temperature ( 200 ℃ ) by combining sol-gel and programmed temperature hydrothermal methods. The composite,Na 4W 10 O 32 /TiO 2,has a uniform mesopore distribution with the average pore diameter of 3.8 nm,and its BET surface area is 178.4 m 2/g. The average size of the composite is below 10 nm. This new photocatalyst exhibited a visible-light photocatalytic activity to decompose para -thion-methyl.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2004年第8期1549-1551,M009,共4页 Chemical Journal of Chinese Universities
基金 国家自然科学基金 (批准号 :2 0 0 710 0 7) 吉林省科技厅社会发展重点项目基金(批准号 :2 0 0 10 40 3 )资助
关键词 孔材料 可见光光催化 杂多酸 锐钛矿 有机磷杀虫剂 Porous materials Visible-light photocatalysis Polyoxometalate Anatase Organophosphorus pesticide
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