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重金属离子对过氧化氢分解催化活性的对比研究 被引量:5

The Study and Contrast ofthe Catalysing Activity of Heavy Metal Ions to the Decomposition of Hydrogen Pexoride
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摘要 过氧化氢(H_2O_2)的稳定性受温度、浓度、pH值,某些阴阳离子等因素的影响,对此已有不少报道[1,2,3]。其中多数报道只限于研究某个pH值、温度和浓度及某种阴、阳离子的影响情况[1~5]本文在H_2O_2初始浓度为0.05mol/L、P、pH值为11时,研究对比了几种重金属离子在不同温度下的催化活性;温度为70℃时,几种重金屑在不同浓度下的催化活性。 This paper,with the decomposition rate of hydrogen peroxide in 30 minutes,studied and contrasted the catalysing activity of some certain heavy metal ions to the decomposition of hydrogen peroxide.The result showed that its catalytic order is Cu^(2+)>Co^(2+)、Ag^+>Mn^(2+)>Ni^(2+)、Pb^(2+).It was also found that in the alkaline solutions, under higher temperature and with certain concentration,some heavy metal ions,to some extent,have some stabilising effect to hydrogen peroxide.
出处 《河北师范大学学报(自然科学版)》 CAS 1993年第1期63-66,共4页 Journal of Hebei Normal University:Natural Science
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  • 2陈士夫,赵梦月,陶跃式,梁新.玻璃纤维附载TiO_2光催化降解有机磷农药[J].环境科学,1996,17(4):33-35. 被引量:123
  • 3高宏成 王文清.钚(Ⅳ)-硝酸根络合常数测定.原子能科学技术,1981,(4):500-503.
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  • 5Vanatta L E, Coleman D E. Reproducible Digestion Method for Ion-Chromatographic Analysis of Anions in 30% Hydrogen Peroxide[J]. J Chromatogr A, 2002, 956: 23-33.
  • 6Doong Ruey-an,Chang Wen-huei.Photoassisted iron compound catalytic degradeation of organophosphorous pesticides with hydrogen peroxide[J].Chemosphere,1998,37(13):2563-2572.
  • 7Zhu Hua,Zhang Manping,Xia Zongfeng,et al.Titanium dioxide mediated photocatalytic degradation of Monocrotophos[J].Wat Res,1995,29(12):2681-2688.
  • 8Ku Young,Wang Wen,Shen Yung-shuen.Reaction behaviors of decomposition of monocrotophos in aqueous solution by UV and UV/O3 processes[J].Journal of Hazardous Materials B,2000,72:25-37.
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