摘要
聚合物生物碱相转移催化剂的合成及其对多类化学反应的催化性能黄锦霞,陈家威,蒋济隆,卢军(湖北大学化学系,武汉430062)(广西师范大学化学系,南宁530001)关键词相转移催化剂,聚合物,生物碱,三相催化,不对称反应相转移催化反应是有机合成中较为活...
olymer-supported alkaloids (quinine and cinchonine )used asphase-transfer catalysts were prepared, which have good catalytic effects on many types of organic reaction (substitution reaction, reductionreaction, Williamson reaction, carbene reaction and synthesis of sulforhodanate, asymmetric addition, asymmetric reduction etc. ). The activities of catalysts with different chain lengths for the substitution reaction were studied.
关键词
聚合物
生物碱
相转移催化剂
合成
phase-transfer catalyst, polymer,alkaloid, three-phasecatalysis, asymmetric reaction