摘要
利用二－（２－乙基已基）磷酸（ＨＤＥＨＰ）、异丙醚和乙醚溶剂萃取Ｉｎ（Ⅲ），并测定了Ｉｎ（Ⅲ）在有机相和水相之间的分配比．Ｉｎ（Ⅲ）在ＨＤＥＨＰ－ＨＮＯ＿３、ＨＤＥＨＰ－ＨＣｌＯ＿４和异丙醚－ＨＢｒ体系中的化学产额依次为９５．２％，９１．７％和８９．２％，在１ｍＬ的ＩｎＣｌ＿３医用放射性核素制剂中，Ｃｕ，Ｆｅ和Ａｇ杂素元素的含量依次不大于０．０４μｇ，０．１５μｇ和２．１μｇ。
The distribution ratioes of the In(Ⅲ )between organic and agueous phases in thesolvent extraction with Di-(2-ethyl hexyl)phosphoric acid( HDEHP),iso-propyl ether , and ethyl ether3re determined.The distribution ratioes of the In(Ⅲ)decreases as the acidity increases in the HDEHP-HNO_3 and HDEHP- HClO_4 system , respectively。 The distribution ratioes of the In(Ⅲ)increaes as theacidity increase in the iso- propyl ether- HBr and ethyl ether-HBr system , respectively,The distributionratioes of the In(Ⅲ) increases as the HDEHP concentration increase and decreases as In(Ⅲ)concentration increase.The distribution ratio of the In(Ⅲ)in order ofdecrease is HDEHP HNO_s,HDEHP- HClO_4 , iso-propyl ether-HBr and ethyl ether- HBr system。 The chemical yield of the In(Ⅲ)inthe HDEHP-HNO_3 , HDEHP-HClO_4 ,iso-propyl ether-HBr system are 95.2%, 91.7%and 89.2%,respectively, The impurities element in 1mL InCl_3 injection solution agent are Cu≤0. 045μg,Fe≤0. 17μg, Ag≤2. 10μ,respectively. This method have been used in the production of the￣(111)In and got rathetgood result.
出处
《四川大学学报（自然科学版）》
CAS
CSCD
1994年第4期489-494,共6页
Journal of Sichuan University(Natural Science Edition)
基金
四川省科委基金
关键词
铟
溶剂萃取
HDEHP
放射性同位素
Indium,solvent extraction,di-(2-ethyl hexyl ) phosphoric acid (HDEHP),injectionSolution agent
