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碱土金属与卤代有机小分子的反应激发函数 被引量:1

The Excitation Functions of the Reactions of Alkaline Earth Metal with Polyatomic Halides
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摘要 In a beam-beam scattering experAnent the excitation fUnctions of the reactions of alkallne earth metals with some polyatoAnc halldes (M+RX- MX+R) have been studied with Laser Induced Fluorescence (LIF) teclmique. At the variation range of the collision energies, the excitation functions can be taken asaR(ET) De In(1 + QMAX/ET)"where ET and QMAX are the coilision energy and the reaction exoergic energy, respectively,and n is a parameter which is correlative to the Illnner of the active vibrational modes in radical R during the reaction processes. Tab1e 2 gives the paramters of the excitation fUllctions for these reactions. In a beam-beam scattering experAnent the excitation fUnctions of the reactions of alkallne earth metals with some polyatoAnc halldes (M+RX- MX+R) have been studied with Laser Induced Fluorescence (LIF) teclmique. At the variation range of the collision energies, the excitation functions can be taken asaR(ET) De In(1 + QMAX/ET)'where ET and QMAX are the coilision energy and the reaction exoergic energy, respectively,and n is a parameter which is correlative to the Illnner of the active vibrational modes in radical R during the reaction processes. Tab1e 2 gives the paramters of the excitation fUllctions for these reactions.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1994年第10期941-946,共6页 Acta Physico-Chimica Sinica
基金 国家自然科学基金
关键词 碱金属 卤代有机物 反应激发函数 Molecular beams, Laser induced fluorescence, Excitation function
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参考文献4

  • 1何国钟,Can J Chem,1988年,66卷,1936页
  • 2王珏,博士学位论文,1986年
  • 3楼南泉,中国科学.B,1982年,9期,285页
  • 4Wu K T,J Phys Chem,1978年,61卷,1064页

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