摘要
结合作者近年来的研究工作 ,对液/ 液两相催化高碳烯烃氢甲酰化的研究进展作一综述 ,针对经典的水/有机两相体系不能用于高碳烯烃氢甲酰化的问题 ,全面介绍了适用于高碳烯烃水/有机两相氢甲酰化的温控相转移催化等 6种改进方法。同时 ,对 90年代以来发展迅速的氟两相、离子液体两相、超临界流体等非水液/液两相体系中的高碳烯烃氢甲酰化作了系统阐述 ,对它们的应用前景进行了评较。
The development in hydroformylation of higher olefins in liquid/liquid biphase systems is reviewed, partially based on the authors' research results in recent years. The classical aqueous/organic biphase system is unsuitable for hydroformylation of higher olefins. In order to solve this problem, six kinds of improved methods including thermo-regulated phase-transfer catalysis are introduced in detail. In addition, the hydroformylation of higher olefins in nonaqueous liquid/liquid biphase systems, such as fluorous biphasic system, non-aqueous ionic liquid and supercritical fluid is also introduced. Meanwhile, the possibilities of commercial applications of each system have been discussed.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2005年第2期209-216,共8页
Progress in Chemistry
基金
国家自然科学基金 (No .2 0 376 0 13
2 990 6 0 0 1
2 9876 0 0 4 )
教育部博士点科研基金 (No .2 0 0 2 0 14 10 0 4 )资助
关键词
氢甲酰化反应
水/有机两相
温控相转移催化
氟两相
离子液体两相
超临界流体
温控相分离催化
hydroformylation
aqueoues/ organic biphase system
thermoregulated phase-transfer catalysis
fluorous biphasic system
non-aqueous ionic liquid
supercritical fluid
thermoregulated phase-separable catalysis
