摘要
研究了旋转园盘电极上脉冲电流电解时的传质过程,建立了脉冲电流电解时传质的双扩散层模型,得到了描述传质过程的扩散方程。并利用混合变量分离、延拓等教学方法解得了旋转园盘电极脉冲电流电解传质过程中反应粒子浓度变化的广义表达式,结果满意。
This paper studied mass transfer process of pulse-current electrolysis on rotating-disc electrode and developed a two diffusiion layer model of mass transfer of pulse-current electrolysis. Also, diffusion equation of describing mass transfer processwas obfained by means of mathematical solutions such as mixed variable departure and extension and so on. So it gaineda broad sense expression of reaction particles centration variation of mass transfer process of pulse-current electrolysis on rotating-disc electrode and the result was satisfying.
基金
浙江省自然基金
关键词
脉冲电流
传质
扩散方程
电解
Rotating-disc electrode
Mass transfer
Pulse current electrolysis
Diffusion equation