期刊文献+

二氧化钛电催化氧化处理甲基橙 被引量:1

Study on the Degradation of Dye Wastewater by Electrochemical Oxidation with Titanium dioxide
在线阅读 下载PDF
导出
摘要 以半导体材料二氧化钛为催化剂,对偶氮染料甲基橙溶液进行了电催化氧化降解实验;考察了催化剂量、槽电压、pH值、电解质浓度、反应时间等因素对处理效果的影响.实验结果表明:二氧化钛的催化效果显著,其色度和COD去除效果可比无催化剂时效果分别提高35%和28%;去除机制主要是电催化体系中产生的·OH对有机物的氧化、降解. As the electrochemical activator, titanium dioxide was introduced to treat methyl orange solution, the typical azo dyes with a novel electric catalysis system. This paper had investigated the effects of activator amount, applied voltage, pH value, electrolysis time on COD and color removal rate. The experiment results indicated that the electric catalytic oxidation process could efficiently remove and degrade methyl orange. color removal and COD removal with titanium dioxide activator could be 35% and 28% more than those without activator respectively. The removal efficiency could be attributed to the oxidation of hydroxyl radicals generated in electric catalysis system.
作者 刘占孟
出处 《怀化学院学报》 2005年第2期52-54,共3页 Journal of Huaihua University
  • 相关文献

参考文献3

二级参考文献21

  • 1谭湘萍,蒋伟川,徐红,王红军.载银TiO_2半导体催化剂对印染废水的光降解研究[J].环境污染与防治,1994,16(5):5-7. 被引量:31
  • 2冀小元,云桂春.H_2O_2-Fe^(2+)/TiO_2-H_2SO_4体系处理废有机溶剂的研究[J].上海环境科学,1996,15(8):33-36. 被引量:9
  • 3朱元保.电化学数据手册[M].长沙:湖南科学技术出版社,1984.208-224.
  • 4Pichat P. Photocatalytic degradation of aromatic and alicyclic pollutants inwater: by products, pathway and mechanism [J]. Wat. Sci. Technol., 1997,35(4): 73-78.
  • 5Huston P L, Pignatello J J. Reduction of perchloroalkanes by ferrioxalate-generated carboxylate radical preceding mineralization by the photo-Fenton reaction [J]. Environ. Sci. Technol., 1996, 30 (12): 3457-3463.
  • 6Ruppert G, Bauer R. The photo-Fenton reaction-an effective photochemical wastewater treatment process [J]. J. Photochem. Photobiol., A: Chem., 1993,73(1):75-78.
  • 7国家环境保护局<水和废水监测分析方法>编委会.水和废水监测分析方法 [M]. (第3版). 北京:中国环境科学出版社, 1997. 372-374.
  • 8San Y, Pignatello J. Photochemical reactions involved in the total mineralization of 2,4-D by Fe3+/H2O2/UV [J]. Environ. Sci. Technol., 1993,27(2): 304-310.
  • 9Delaat J, Gallard H, Ancelin S, et al. Comparative study of oxidation of atrazine and acetone by H2O2/UV, Fe(III)/UV, Fe(III)/ H2O2/UV and Fe(II) or Fe(III)/H2O2 [J]. Chemospere, 1999,39 (15): 2693-2706.
  • 10Hideki K. Steady-state concentration of hydroxyl radical in titanium dioxideaqueous suspensions [J]. Chemospere, 1991, 22 (11): 1003-1009.

共引文献62

同被引文献9

引证文献1

二级引证文献11

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部