摘要
以Ｃｅ￣（４＋）／Ｃｅ￣（３＋）为间接电氧化还原体系，在相转移催化剂ＰｈＣＨ＿２Ｎ（Ｃ＿２Ｈ＿５）＿３Ｃｌ存在下，对肟类化合物进行选择性间接电氧化。结果表明，在室温条件下，电解２ｈ，肟类能被选择性地氧化为相应的羰基化合物。收率７５～９５．６％。
Indirect electrooxidation of oximes was studied by using Ce(Ⅳ)/Ce(Ⅲ)as a redox systemin the presence of phase transfer catalyst PhCH_2N(C_2H_5)_3Cl. The results showed that at the ambient temper-ature,the oximes could be selectively oxidized in two hours to the corresponding carbonyl compoundsy with out deep oxidation, The yields are from 75%to 95.6%
出处
《合成化学》
CAS
CSCD
1995年第3期279-281,共3页
Chinese Journal of Synthetic Chemistry
基金
河南省教委自然科学基金资助项目
关键词
间接电解氧化
肟
选择性氧化
Phase transfer catalysis,Indirect electrical oxidation,Oxime,Selective oxidation.
