摘要
溶剂、酸度及表面活性剂对三卤代偶氮氯膦光度法测定La(Ⅲ)的选择性影响袁黎明(北京理工大学化工与材料学院北京100081)摘要*本文较详细探讨了酸度、乙醇、异丙醇、丙酮、吐温-80、OP对三氯偶氮氯膦、三溴偶氮氯膦、二溴一氯偶氮氯膦分别测定稀土元素L...
In this paper, the effects of ethanol, isopropanol, acetone, Tween-80 or op on the selectivityof determination of La(Ⅲ) with TBCPA, TCCPA orDBCCPA have been studied. The results of researchof eighteen colour reactions showed that the selectivity of colour reactions could be improved markedlyby adding ethanol, isopropanol, acetone, Tween-80 orOP. The higher the acidity of the solution, the better the improvement in selectivity.
出处
《化学试剂》
CAS
CSCD
北大核心
1995年第5期271-273,共3页
Chemical Reagents
关键词
三卤代偶氮氯膦
镧
光度法
trihalogenated CPA, La(Ⅲ), selectivity, spectrophotometric method