摘要
毛细管气相色谱法测定热不稳定有机磷农药辛硫磷顾明松，罗毅（军事医学科学院毒物药物研究所北京１００８５０）１前言热不稳定化合物的气相色谱分析是色谱工作者一直在设法解决的难题，已有冷柱头（ｃｃｏｌｏｎ－ｃｏｌ－ｕｍｎ）和电子压力程序控制进样（ＥＰＣ）等方...
he thermo-labile organophosphorous pesticide Phoxim was determined by capillary gas chromatographywith flame phototnetric detector. When high linear velocity H_2(>200cm/s) was used as carrier gas,the thermo-decomposition of Phoxim was considerably reduced.The most important gas chromatography conditions,injectortempereture and column head pressure,were studied.The thermo-decomposition preducts were identified by gaschromatography-mass spectrometry.Under higher column head pressure,the sample size can be increased to 4μLby still keeping the response within linear range.
出处
《色谱》
CAS
CSCD
北大核心
1995年第6期470-471,476,共3页
Chinese Journal of Chromatography
关键词
有机磷农药
气相色谱
辛硫磷
capillary gas chromatography,organophosphorous pesticides,phoxim
