摘要
以苯氧乙醇为起始剂合成了两种新型氮支套索冠醚:N-苯氧乙基单氮杂-18-冠-6(18CE)与N-苯氧乙基单氮杂-15-冠-5(15CE).通过红外光谱、核磁共振氢谱、紫外光谱和元素分析表征了新冠醚及其中间体的结构.测试了18CE与15CE络合阳离子对溶液电导率的影响.
By using phenoxyethanlo as initial material, two new N-pivot lariat crown ethers were synthesized——N-phenoxyethyl-18-crown-6（18CE） and N-phenoxyethyl moroaza-15-crown-5 （15CE）. The structures of the new crown ethers and the intemaediate compounds are characterized by FTIR, ^1H NMR and UV spectra and elemental analysis. It is measured that influence of the 18CE and 15CE complex ions for solution conductance.
出处
《烟台师范学院学报（自然科学版）》
2005年第3期211-214,共4页
Yantai Teachers University journal(Natural Science Edition)
关键词
氮支套索冠醚
合成
表征
电导率
N-pivot lariat crown ether
synthesis
characterization
conductance
