期刊文献+

氰酸酯及其改性树脂体系的反应动力学研究 被引量:9

Study on kinetics of cyanate esters and its modified resin
在线阅读 下载PDF
导出
摘要 利用傅立叶变换红外光谱对纯氰酸酯及其改性树脂体系进行固化反应动力学的研究。研究表明,氰酸酯主催化剂能降低反应活化能,使固化反应速度明显加快,反应温度降低;而苯酚的加入可明显提高改性体系的最大固化度。 The kinetics of neat cyanate ester and its modified resin systems were investigated by FTIR. The results showed the catalyst could reduce the active energy of resin, thus the reaction rate could be accelerated and reaction temperature could be reduced remarkably. Furthermore, the phenol could increase the maximum degree of cure of modified resin.
出处 《热固性树脂》 CAS CSCD 2006年第1期12-15,共4页 Thermosetting Resin
关键词 傅立叶变换红外光谱 反应动力学 氰酸酯 FTIR reaction kinetics cyanate ester
  • 相关文献

参考文献7

  • 1D A Shimp, J R Christenson, S J Ising. Cyanate esters: an emerging family of versatile composite resins [ J ]. 34 th Int SAMPE Symp Exhib, 1989, 34: 222-233.
  • 2D A Shimp, F A Hudock, W S Bobo. Toughening cyanate functional resins for structural composite matrix apphcation [J]. 18 th Int SAMPE Tech Conf, 1986, 18: 851-862.
  • 3李文峰,辛文利,梁国正,马晓燕,朱光明.氰酸酯树脂的固化反应及其催化剂[J].航空材料学报,2003,23(2):56-62. 被引量:35
  • 4In: Hamerton I, ed. Chemistry and Technology of Cyanate Esters [M]. Glasgow: Chapman and Hall, 1994.
  • 5A Osei- Owusu, G C Martin. Catalysis and Kinetics of Cyclotrimerization of Cyanate Ester Resin Systems [J]. Polymer Engineering and Science, 1992, 32: 8.
  • 6S L Simon, Gill. Cure kinetics of a thermosetting liquid dicyanate ester monomer high Tg polycyanate material [J]. Appl Polym Sci.1993, 47: 461-485.
  • 7Grenier, Loustalo, et al. A study of the mechanisms and kinetics of themolten state reaction of non-catalyzed cyanate and epoxy/cyanate systems [J]. Eur Polym, 1995, 31: 1139-1153.

二级参考文献1

共引文献34

同被引文献78

引证文献9

二级引证文献26

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部