摘要
综述了对液/液两相催化高碳烯烃氢甲酰化制备高碳醇的研究进展,针对经典的水/有机两相体系不能用于催化高碳烯烃氢甲酰化的问题,全面介绍了适用于水/有机两相体系中高碳烯烃氢甲酰化的温控相转移催化法等6种改进方法。同时对氟两相、离子液体两相、超临界流体等非水液/液两相体系中的高碳烯烃氢甲酰化作了系统阐述,并对它们的应用前景进行了评价。
The advances in hydroformylation of higher olefins to higher alcohol in liquid/liquid biphase systems were reviewed.Aiming at the problems that the classical aqueous/organic biphase system is unsuitable for the hydroformylafion of higher olefins, six kinds of improved methods including the thermoregulated phase-transfer catalysis were introduced in detail. In addition,the hydroformylation of higher olefins in nonaqueous liquid/liquid biphase systems, such as the fluorous biphasic system, non-aqueous ionic liquid biphasic system and supercfitical fluid biphasic system, were also introduced. Meanwhile, the possibilities of commercial applications of each system were discussed.
出处
《现代化工》
EI
CAS
CSCD
北大核心
2006年第1期10-14,16,共6页
Modern Chemical Industry
基金
教育部博士点科研基金资助项目(20020141004)
国家自然科学基金资助项目(20376013)
关键词
高碳烯烃
氢甲酰化
高碳醇
水/有机两相
温控相转移催化
higher olefins
hydroformylation
higher alcohol
water/organic biphase
thermoregulated phase-transfer catalysis
