期刊文献+

环己烷分子氧选择性氧化固体催化剂研究进展 被引量:4

Research progress of solid catalysts for selective oxidation of cyclohexane using oxygen
在线阅读 下载PDF
导出
摘要 对环己烷分子氧催化氧化制环己酮固体催化剂的最新进展进行了综述,重点介绍了贵金属催化剂、过渡金属及其氧化物催化剂和分子筛催化剂。指出锆基复合氧化物催化剂和负载在分子筛上的金催化剂具有较高的催化活性和选择性及好的稳定性,具有一定的应用及工业化前景。 The research progress of solid catalysts for selective oxidation of cyclohexane to cyclohexanone using oxygen was reviewed, emphatically precious metal catalysts, transition metal catalysts, oxide catalysts and molecular sieve catalysts. Zirconbased composite oxide catalyst and gold catalyst loaded on molecular sieve showed relatively high catalytic activity , selectivity and stability and had expected application and commercialization prospects.
出处 《合成纤维工业》 CAS CSCD 北大核心 2006年第1期45-48,共4页 China Synthetic Fiber Industry
基金 国家自然科学基金项目(20376073)
关键词 环己烷 环己酮 分子氧 选择性 氧化 固体催化剂 进展 cyclohexane cyclohexanone molecular oxygen selectivity gold oxidation solid catalyst progress
  • 相关文献

参考文献32

  • 1刘小秦.环己酮生产工艺的发展及研究进展[J].化工进展,2003,22(3):306-309. 被引量:28
  • 2Clark J H. Catalysis for green chemistry [ J]. Pure and Applied Chemistry, 2001, 73(1) : 103 - 111.
  • 3尉士民,杜芳林,张志琨.CO氧化催化剂研究进展[J].工业催化,2003,11(1):31-36. 被引量:7
  • 4OConnor R P, Klein E J, Henning D, et al. Tuning millisecond chemical reactors for the catalytic partial oxidation of cyclohexane[J], Applied Catalysis A: General, 2003, 238(1): 29 -40.
  • 5Jun K W, Kim S B, Kim S B, et al. Process for preparing cyclohexanol and cyclohexanone [ P]. US Pat Appl, US 6 075 170.2000.
  • 6Haruta M, Yamada N, Kobayashi T, et al. Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide [ J]. Journal of Catalysis, 1989, 115 (2) :301 - 309.
  • 7Haruta M, Tsubota S, Kobayshi T, et al. Low-temperature oxidation of CO over gold supported on TiO2, Alpha-Fe203, and Co304[J]. Journal of Catalysis, 1993, 144(1): 175 -192.
  • 8Haruta M, Date M. Advances in the catalysis of Au nanoparticles[J]. Applied Catalysis A: General, 2001, 222(1-2): 427 -437.
  • 9Haruta M. Gold as a novel catalyst in the 21st century: Preparation, working mechanism and Applications [ J]. Gold Bulletin,2004, 37 (1-2): 27-36.
  • 10Druliner J D, Herron N, Kourtakis K. Direct oxidation of cycloalkanes [ P]. US Pat Appl, US 6160183. 2000.

二级参考文献40

共引文献33

同被引文献56

引证文献4

二级引证文献12

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部