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聚乙烯吡咯烷酮抑制水合物生成研究 被引量:14

RESEARCH WORKS ABOUT PVP INHIBITION PERFORMANCE ON NATURAL GAS HYDRATE
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摘要 对聚乙烯吡咯烷酮(PVP)在4℃、8.27MPa附近压力下对天然气水合物的抑制性能进行了实验,结果表明,PVP可以明显抑制水合物的生成,但不同分子量段的PVP有着不同的抑制效果:PVPK17因为分子量太小,几乎没有抑制作用;PVPK30有一定的抑制作用;而PVPK90则有着很好的抑制效果,能在实验条件下抑制1200min没有水合物的生成。另外发现,不同浓度的PVP对天然气水合物的抑制效果也不相同:对于PVPK30,1%浓度比0.5%浓度的抑制效果好;而对于PVPK90,则1%浓度的抑制效果比0.5%和2%浓度的要好。 Experiments are conducted on inhabitation performance of polyvinylpyrrolidone (PVP) on natural gas hydrate under the condition of temperature 4 ℃ and pressure 8.27 MPa. The experiment results show that PVP can obviously prevent hydrate, and PVP with different molecular weights has different inhibition effectiveness: PVPK17 nearly has no inhibition effect because of its small molecular weight; PVPK30 has mild inhibition effect; while PVPK90 can inhibit natural gas from hydrate for continuous 20-hr in laboratory conditions with superior inhibition performance. Another discovery is made that PVP with different concentrations has different inhibition effect on natural gas: PVPK30 with 1% concentration are more effective than that of 0.5%, while PVPK90 with 1% concentration is better than that of 0.5% and 2%.
出处 《天然气工业》 EI CAS CSCD 北大核心 2006年第3期125-128,共4页 Natural Gas Industry
基金 国家自然科学基金西部重大研究计划项目资助(90410003)
关键词 天然气 水合物 动力学 抑制剂 聚乙烯吡咯烷酮 分子量 浓度 效果 natural gas, hydrate, dynamics, inhibitor, Polyvinylpyrrolidone (PVP), molecular weight, concentration, effectiveness
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  • 1[1]Sloan E D. Clathrate Hydrate, Mercel Decker, Inc NY, 1990
  • 2[2]Duncum S N et al. Eur. Pat.,1993;536~950
  • 3[3]Anselme M J et al. World Pat. WO 1993, 93/25798
  • 4[4]Sloan E D, World Pat. WO 1994, 94/12761
  • 5[5]Kelland M A et al.Control of gas hydrate formation by surfactants and polymers. SPE 28506, 1994
  • 6[6]Lederhos J P et al. Effective kinetic inhibitors for natural gas hydrates. Chem. Eng. Sci., 1996;(51):1 221~1 229
  • 7[7]Cohen J M et al. Enhanced hydrates inhibitors:Powerful synergism with glycol ethers. Energy & Fuels, 1998;12:216~218
  • 8[8]Rodger P M.Simulation of surface melting and inhibition in clathrate hydrates. 8th International Symposium on Molecular Recognition and Inclusion, 1994
  • 9[9]Ruoff P, Lekvam K.A reaction kinetic mechanism for methane hydrate formation in liquid water. J. Am. Chem. Soc. , 1993, 115, 8 565
  • 10[10]Yuliev M and Gazov D, (RUSS), 1972;(10):17~19

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