摘要
以加工加氢渣油的茂名石化3#重油催化裂化装置的工业数据为基础,针对加氢渣油的特点,提出了以渣油四组分作为划分原料集总基础的催化裂化七集总动力学模型。通过变尺度法(B-F-G-S)和龙格库塔法确定动力学参数,并通过工业实测数据验证,表明该模型具有良好的拟合性和外推性,较好地反映了加氢渣油催化裂化反应规律。
According to the commercial data of 3^# RFCCU processing hydrotreated residuum in Maoming petrochemical company and the character of hydrotreated residuum, the kinetic model with 7 lumps for hydrotreated residuum fluid catalytic cracking based on the four-component of residual was presented. Its reaction rate constants were determined by B-F-G-S and RungeKutta. The verification results by commercial data showed that the model was reliable, fitted well and reflected the reaction rules of hydrotreated residuum fluid catalytic cracking.
出处
《石油学报(石油加工)》
EI
CAS
CSCD
北大核心
2006年第4期44-48,共5页
Acta Petrolei Sinica(Petroleum Processing Section)
基金
中国石油化工股份有限公司资助项目(104081)
关键词
加氢渣油
催化裂化
动力学模型
集总
四组分
hydrotreated residuum
fluid catalytic cracking
kinetic model
lump
fourcomponent