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N_2S_2类双功能联接剂前体的合成研究 被引量：3

Study on Synthesis of the Precusor of N_2S_2 Series Bifunctional Coupling Agent
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摘要 以半胱胺为原料,合成了N2S2类双功能联接剂前体即N-(2”-对甲氧苄巯乙基)-2-[(2’-对甲氧苄巯乙基)氨基]乙酰胺。介绍了两种合成方法的技术路线及操作过程,并给出了产率。通过IR1、HNMR等对中间产物及产物进行了确证。此外,将合成的化合物制成更稳定且易于保存的盐酸盐,并经IR等进行了检验,确定了此处理是合理可行的。 N - [ 2＂ - （4 - methoxybenzylmercapto） ethyl ] - 2 - [ （2＇ - （4 - methoxybenzylmercapto） ethyl） amino ] acetamide as the precuror of N2 S2 series bifunetional coupling agent （BFCA） was synthesized by using Cysteamine as raw material. The intermediate and the final product were investigated by IR and ^1HNMR. The hydrochloride of this compound was prepared, which is more stable than its chelators, the feasibility of this method was also testified by measuring some relevant spetroseopic properties of samples as prepared.
作者 宋宏涛 魏洪源 罗顺忠 楚士晋
机构地区 西南科技大学材料科学与工程学院 中国工程物理研究院核物理与化学研究所
出处 《西南科技大学学报》 CAS 2006年第3期27-30,共4页 Journal of Southwest University of Science and Technology
关键词 双功能联接剂 N2S2类双功能联接剂前体 合成 bifunctional coupling agent N2S2 series bifunctional coupling agent precusor synthesis
分类号 O621.3 [理学—有机化学]
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参考文献12

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同被引文献26

  • 1张炜,江涛,任素梅,管华诗.环糊精金属配合物模拟金属蛋白酶的研究进展[J].化学试剂,2005,27(3):145-148. 被引量：3
  • 2林伟,彭亦如,陈奎治,翁家宝,徐国兴.光谱分析法研究四磺酸酞菁金属配合物与牛血清白蛋白的结合作用[J].分析化学,2006,34(3):411-414. 被引量：8
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  • 8宋宏涛 罗顺忠 高晖 等.草酸在铼氧配合物制备过程中的作用研究.化学试剂,2008,30:135-138.
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西南科技大学学报
2006年 第3期

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