摘要
制备了苯乙烯(St)、St与丙烯酸(AA)混合物、丙烯酸接枝聚丙烯(PP-g-AA)改性聚丙烯/聚苯乙烯(PP/PS)共混物以及AA,St改性PP(原位形成PP/PS共混物)。用差示扫描量热仪(DSC)研究了3种改性方法对共混物中PP结晶与熔融行为的影响。结果表明,PS对PP的结晶与熔融温度影响不大,PP-g-AA则提高共混物中PP的结晶温度。St以及St与AA混合单体对PP/PS中PP结晶温度影响不大,但AA改性提高PP/PS中PP结晶温度。St加入PP导致PP结晶温度下降,St与AA混合单体原位聚合则提高PP的结晶温度。改性对共混物中PP的熔融温度影响不大,但是熔融峰形与结晶温度高低有关。红外光谱证实St与AA混合单体改性PP中有PP-g-AA形成,但改性共混物中没有PP-g-AA形成。
PP/PS blends modified by PP-g-AA or reactive monomer, such as acrylic acid （AA） and styrene （St） were prepared. Crystallization and melting behavior were investigated by DSC. The results indicate that addition of PS has little influence on the crystallization temperature of PP. Addition of PP g AA can increase significantly the crystallization temperature of PP in the blends. Although addition of St or AA/St comonomer hardly influences the crystallization temperature of PP in the blends, an increase in the crystallization temperature of PP in the blends is observed by addition of AA. St added into PP causes fall of crystallization temperature of PP, and St and AA added into PP cause rise of crystallization temperature of PP. All blends show no remarkable variety in melting temperature, but the shapes of melting peak depend upon the crystallization temperature of PP in the blends. IR results indicate that addition of AA and St into PP results in the formation of PP-g-AA, but no PP-g-AA is formed in PP/PS blends modified by AA and St.
出处
《现代塑料加工应用》
CAS
北大核心
2006年第5期11-15,共5页
Modern Plastics Processing and Applications
基金
国家自然科学基金(50573094)
广州市科技计划(2005Z3-D2131)
关键词
聚丙烯
聚苯乙烯
苯乙烯
丙烯酸
接枝
共混
结晶
熔融
polypropylene
polystyrene
styrene
acrylic acid
grafting
blend
crystallization
melting
