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Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na_2(A^1∑_u^+,v=8-b^3∏_(0u),v=14)-Na System

Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na2(A^(1)∑u^(+),ν=8~b^(3)∏0u,ν=14)-Na System
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摘要 Here wc report calculation of the differential interference angles (including b≤p gild b≥p ) for singlet-triplet mixed states of Na2(A^1∑u^+,ν=8-b^3∏0u,ν=14) system in collision with Na, in order to study the collision- induced quantum interference on rotational energy transfer in an atom-diatom system. The calculation is based on the first-order Born approximation of time-dependent perturbation theory, and the anisotropic Lennard-Jones intcraction potentials are also employed, The relationships between differential interference angle and impact parameter, including collision diameter and velocity, are obtained,
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第6期469-472,共4页 化学物理学报(英文)
基金 This work was supported by National Natural Science Foundation of China(No.10374040).
关键词 Rotational energy transfer Collision induced quantum interference Interference angle 转动传能 碰撞诱导量子干涉 干涉角
分类号 O [理学]
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