期刊文献+

磺基琥珀酸双2-丁基辛酯钠盐的合成及表面活性测定 被引量:2

Synthesis and Surface Activity Determination of Sodium Di(2-butyl-octyl) Sulfosuccinate
在线阅读 下载PDF
导出
摘要 以马来酸酐和2-丁基辛醇为原料,经酯化得到相应的双酯,以乙醇作混相促进剂,使双酯与亚硫酸氢钠进行磺化反应,合成了磺基琥珀酸双2-丁基辛酯钠盐。采用正交试验对酯化反应条件进行了优化。合成产物的临界胶束浓度(cmc)值为3.58×10-6mol/L,表面张力(γcmc)为27.568mN/m。 Maleic anhydride and 2 - butyl - 1 - octanol was esterfied to produce corresponding diester. Sodium di (2 -butyl - octyl) sulfosuccinate was synthesized by sulfonation of the ester and sodium bisulfite using ethanol as phase - blending accelerator. The esterification conditions were optimized by orthogonal test. The value of cmc and the surface tension(γcmc) of the product were 3.58 × 10^-6 mol/L and 27.568 mN/m respectively.
出处 《精细石油化工进展》 CAS 2006年第12期4-6,共3页 Advances in Fine Petrochemicals
关键词 磺基琥珀酸双酯钠盐 表面活性剂 表面张力 临界胶束浓度 sulfosueeinate diester, surfactant, surface tension, critical micelle concentration
  • 相关文献

参考文献12

二级参考文献29

共引文献87

同被引文献53

  • 1郑延成,韩冬,杨普华,王红庄.双尾烷基硫酸盐的合成与表面性质[J].日用化学工业,2006,36(3):137-139. 被引量:12
  • 2华平,李建华,戴宝江.醇醚辛基磺基琥珀酸混合双酯钠的合成与性能研究[J].化学试剂,2007,29(8):459-462. 被引量:2
  • 3O'Lenick A J Jr. Guerbet chemistry [J]. J Sur Deter, 2001, 3 (4): 311-315.
  • 4Kozlowski J T, Davis R J. Heterogeneous catalysis for the Guerbet coupling of alcohols[J]. ACS Catal, 2013, 3(7): 1588- 1600.
  • 5陈晓伟,梁宇翔.格尔伯特醇的制备方法:CN,1939886A[P],2007-04-04.
  • 6Kourtakis K, Ozer K R. Lanthanum-promoting supported metal catalysts and process for producing Guerbet alcohols using same: US, 7807857 B2[P]. 2010-10-05.
  • 7高平,刘维民,梁永民,等.格尔伯特醇的制备方法:CN,102020533A[P],2011-04-20.
  • 8Tanaka Y, Utsunomiya M. Process of producing alcohol: U'S, 8318990 B2[P]. 2012-11-27.
  • 9Carlini C, Macinai A, Galletti A M R, et al. Selective synthesis of 2-ethyl-l-hexanol from n-butanol through the Guerbet reaction by using bifunctional catalysts based on copper or palladium precursors and sodium butoxide[J]. J Mol Catal A: Chem, 2004, 212: 65-70.
  • 10Birky T W, Kozlowski J T, Davis R J. Isotopic transient analysis of the ethanol coupling reaction over magnesia [J]. J Catal, 2013, 298: 130-137.

引证文献2

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部