摘要
由邻香兰素缩邻苯二胺(以L表示)与稀土硝酸盐合成了2种新固体配合物。并对合成的配合物进行了元素分析和红外光谱、紫外光谱、差热—热重、摩尔电导分析,确定配合物的组成为〔LnL(NO3)2〕NO3(Ln=La,Tb),推断出了配合物可能的结构。
Two new solid complexes of lanthanoid nitrates with bis schiff base (L) derived from o vanillin and o phenylenediamine have been synthesized and characterized by elemental analysis,DTA TG,IR,uv,molar conductance analysis.The composition of the complexes was confirmed to be LnL(NO 3) 2 NO 3 (Ln=La,Tb).The possible structure and some properties of the complexes were studied.
出处
《山东建材学院学报》
1996年第3期76-78,共3页
Journal of Shandong Institute of Building Materials
关键词
双希夫碱
稀土硝酸盐
配合物
bis schiff base
lanthanoid nitrate
complex