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高温合成Co_3O_4制备的负极材料的性能 被引量:1

Performance of anode material prepared by high temperature synthesized Co_3O_4
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摘要 在不同温度下烧结Co(OH)2制备了Co3O4,然后加入10%的Mn粉作为催化剂,得到锂离子电池负极材料,并进行了电化学性能测试。以40 mA/g充放电,700℃下合成的Co3O4制备的负极材料的循环性能较好,首次充电容量为758.2mAh/g,首次充放电效率为81.9%,50次循环后的容量保持率为81%,库仑效率在98%以上。 Co3O4 was obtained by sintering Co(OH)2 at different temperature, then 10% Mn powder was added as catalyst to obtain the anode material. The electrochemieal performance was tested. When eharge-diseharge at 40 mA/g, the anode material prepared by Co3O4 synthesized at 700℃ showed a initial eharge capacity of 758.2 mAh/g and better cycle performanee, its initial eharge-discharge effieieney was 81.9%, the capaeity retention was 81% after 50 eyeles, the coulombie efficiency was above 98%.
出处 《电池》 CAS CSCD 北大核心 2007年第1期55-56,共2页 Battery Bimonthly
关键词 锂离子电池 CO3O4 CO(OH)2 Li-ion battery Co3O4 Co(OH)2 manganese
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参考文献3

  • 1陈敬波,胡国荣,彭忠东,陈艳玲,桂阳海.锂离子电池氧化物负极材料研究进展[J].电池,2003,33(3):183-186. 被引量:11
  • 2Paul A C,John T S I.Combined X-ray study of lithium(tin)cobalt oxide matrix negative electrodes for Li-ion batteries[J].Electro-chimica Acta,2002,47(18):2 885-2 892.
  • 3Wang G X,Chen Y,Konstantinov K,et al.Investigation of cobalt oxides as anode materials for Li-ion batteries[J].J Power Sources,2002,109(1):142-147.

二级参考文献30

  • 1刘伟峰.[D].北京:中国科学院物理所,1997.
  • 2华寿南 杨晓燕 康石林 etal.掺杂Sn的Li4Ti5O12作为锂离子电池负极研究[A]..Proceeding of the 24th China Nat.onal Conferences on Chemical and Physical Power Sources(第二十四届中国化学与物理电源学术年会论文集)[C].Harbin(哈尔滨),2000.304—305.
  • 3小柴信晴.新素材,1996,8:13-16.
  • 4Courtney I A. Dhan J R. Key factors controlling the reversibility of the reaction of lithium with SnO2 and SnBPO6 [ J ]. J Electrochem Soc.1997,144:2943-2948.
  • 5Courtney I A, Dhan J R. Electrochemical and in-situ X-ray diffraction studies of the reaction of lithium with the oxide composite[J]. J Electrochem Soc, 1997, 144:2045 -2052.
  • 6Liu W F, Wang Z X, Li H, et al. Studies of stannic oxide as an anode material for lithium-ion batteries[J]. J Electrochem Soc, 1998,145 : 59 - 62.
  • 7Idota Y, Kuhota T, Matsufuji A, et al. Tin-based amorphous oxide:a high capacity lithium-ion storage material[ J ]. Science, 1997, 276:1395 - 1397.
  • 8Sakamoto J S, Huang C K, Surampudi S, et al. Effects of particle size on SnO electrode performance in lithium-ion cells[J ]. Materials Letters, 1998, 33(5 - 6) :327 - 329.
  • 9Yu A, French R. Mesoporous tin oxides as lithium intercalation anode materiah[J ]. J Power Sources, 2002,104(1 ) : 97 - 100.
  • 10Abraham K M. Pasquariell D M, Willstaedt E B. Preparation and characterization of some lithium insertion anodes for lithium batteries[J]. J Electrochem Soc, 1990, 137(3):743- 749.

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同被引文献65

  • 1杨遇春.二次锂电池进展[J].电池,1993,23(5):230-233. 被引量:8
  • 2张世超.锂离子电池关键材料产业技术现状与发展趋势[J].新材料产业,2006(3):32-36. 被引量:3
  • 3郭炳棍,徐徽,王先友,等.锂离子电池[M].长沙:中南大学出版社,2002.
  • 4Brandt K. Historical Development of Secondary Lithium Batter- ies[J]. Solid State Ionics, 1994, 69(3-4): 173-183.
  • 5"Ohzuku T, Brodd R. An Overview of Positive-electrode Materi- als for Advanced Lithium-ion Batteries[ J ]. J Power Sources,2007, 174 (2) : 449 -456.
  • 6Shi H, Barker J, Saidi M Y, et al. Structure and Lithium In- tercalation Properties of Synthetic and Natural Graphite [ J ]. J Electro- chem. Soc, 1996, 145 ( 11 ) : 3466 - 3472.
  • 7Endo M, Kim C, Nishimura K. Recent Development of Carbon Materials for Li -ioh Batteries[J]. Carbon, 2000, 38(2) : 183 -197.
  • 8Ein-eli Y, Koch V R. Chemical Oxidation: a Route to En- hanc.ed Capacity in Li-ion graphite anodes [ J ]. J Electrochem Soc, 1997, 1,44(9) : 2968 -2973.
  • 9Pistoia G. Lithium batteries-New materials, Development ant1 perspectives [ M ]. Amsterdam : Elsevier, 1994 : 1 - 97.
  • 10Takami N, Satoh A, Hara M. Rechargeable Lithimn-ion Cells Using Graphitized Mesophase-pitch-based Carbon Fiber Anodes [ J ] J Electrochemical Soc, 1995, 142(8) : 2564 -2571.

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