摘要
合成了2,2-二苯基-2-羟基乙酸苯胺加合物(1),其结构经UV,IR和X-射线单晶衍射仪表征。1的分子式为C34H31NO6,分子量为549.60,晶体属于三斜晶系,P1空间群,晶胞系数为:a=8.646(16),b=13.357(2),c=14.117(3),α=69.685(3)°,β=77.593(3)°,γ=71.748(3)°,V=1.441 3(5)nm3,Z=2,Dr=1.266 mg.cm-3,F(000)=580,μ(Mo Kα)=0.087 mm-1。结构由直接法解出,最终偏离因子为R1=0.054 6,wR=0.123 3。1通过分子间氢键连接形成超分子化合物。
A novel 2,2-diphenyl-2-hydroxyactic acid and aniline adduct（ 1 ） was synthesized. Its composition and structure were characterized by UV, IR and x-ray single crystal diffraction. The resuits showed that 1（ C34H31NO6 ）belongs to triclinic system and space group P1, with unit cell constants a=8.646（16）,b=13.357（2）,c=14.117（3）,α=69.685（3）°,β=77.593（3）°,γ=71.748（3）°,V=1.441 3（5）nm^3,Z=2,Dr=1.266 mg.cm-3,F（000）=580,μ（Mo Kα）=0.087 mm^-1, R1 =0.054 6, wR2 =0. 123 3. The supermolecular structure was formed by hydrogen bond between molecules of 1.
出处
《合成化学》
CAS
CSCD
2007年第4期442-446,共5页
Chinese Journal of Synthetic Chemistry
