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CO_2加氢直接制取二甲醚的研究 被引量:39

Direct Synthesis of DME from CO 2 and H 2
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摘要 CO2加氢直接制取二甲醚的研究葛庆杰黄友梅1)邱凤炎李树本(中国科学院兰州化学物理研究所兰州730000)关键词二氧化碳催化加氢二甲醚铜催化剂分类号O643.32二氧化碳在地球上含量极丰富,且随着工业的发展而日益增长.同时二氧化碳含量的日益增多,会加... The effects of catalyst reduction temperature and reaction conditions on the reaction of CO 2 hydrogenation to dimethyl ether were investigated. The following results were obtained:① Catalyst reduction temperature has no evident effect on the reaction, the suitable reduction temperature ranges from 240℃-270℃; ② With increasing reaction temperature, CO 2 conversion and CO selectivity increase, but DME selectivity decreases. Above 240℃, CO 2 conversion decreases with increasing reaction temperature. ③ Increasing pressure and decreasing GHSV are benificial to the reaction of CO 2 hydrogenation to DME, with increases of CO 2 conversion and DME selectivity and decrease of selectivity to byproduct CO.
出处 《分子催化》 EI CAS CSCD 北大核心 1997年第4期297-300,共4页 Journal of Molecular Catalysis(China)
关键词 二氧化碳 催化 加氢 二甲醚 催化剂 Carbon dioxide, Catalytic hydrogenation, Dimethyl ether, Copper catalyst
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