摘要
CO2加氢直接制取二甲醚的研究葛庆杰黄友梅1)邱凤炎李树本(中国科学院兰州化学物理研究所兰州730000)关键词二氧化碳催化加氢二甲醚铜催化剂分类号O643.32二氧化碳在地球上含量极丰富,且随着工业的发展而日益增长.同时二氧化碳含量的日益增多,会加...
The effects of catalyst reduction temperature and reaction conditions on the reaction of CO 2 hydrogenation to dimethyl ether were investigated. The following results were obtained:① Catalyst reduction temperature has no evident effect on the reaction, the suitable reduction temperature ranges from 240℃-270℃; ② With increasing reaction temperature, CO 2 conversion and CO selectivity increase, but DME selectivity decreases. Above 240℃, CO 2 conversion decreases with increasing reaction temperature. ③ Increasing pressure and decreasing GHSV are benificial to the reaction of CO 2 hydrogenation to DME, with increases of CO 2 conversion and DME selectivity and decrease of selectivity to byproduct CO.
出处
《分子催化》
EI
CAS
CSCD
北大核心
1997年第4期297-300,共4页
Journal of Molecular Catalysis(China)
关键词
二氧化碳
催化
加氢
二甲醚
铜
催化剂
Carbon dioxide, Catalytic hydrogenation, Dimethyl ether, Copper catalyst