摘要
在水溶液中合成了5种固态含能配合物M(ATZ).nH2O(M=Mn,N i,Zn,n=6;M=Co,Pb,n=3;ATZ=5,5’-偶氮四唑),并对它们进行了表征。用RD496-CK2000微热量计测定了298.15 K下各配合物的液相生成反应焓变ΔrHmθ均为负值,有利于目标物生成;并改变反应温度,研究了它们的液相生成反应的热动力学。
Five solid energetic complexes M （ATZ） · nH2O （ M = Mn, Ni, Zn, n = 6 ; M = Co, Pb, n = 3 ; ATZ = 5,5＇ - azotetrazole） have been synthesized and characterized. The enthalpy changes of liquid phase reaction, △rHm^θ, investigated by RD496 - CK2000 microcalorimeter, are all negative. The experimental results reveal that the exothermic reaction benefit the proceeding of the reactions and thus provide a thermodynamic reason for the occurrence of the reactions. In addition, thermodynamic of liquid phase reaction is studied by changing temperature.
出处
《延安大学学报（自然科学版）》
2008年第1期41-45,共5页
Journal of Yan'an University：Natural Science Edition
基金
国家自然科学基金(20771089)
陕西省自然科学基金(2007B02)
延安大学校级科研项目(YDK2005-020)
关键词
含能配合物
液相生成反应
热动力学
energetic complex
liquid phase reaction
thermokinetic
