摘要
介绍了Cu/ZrO2催化剂的制备方法,阐述了助剂对Cu/ZrO2催化剂物化及催化性能的影响,综述了Cu/ZrO2催化剂在CO和/或CO2加氢合成甲醇、醇类水蒸气重整制氢、二乙醇胺脱氢合成亚氨基二乙酸盐、环己醇脱氢制环己酮和环己醇还原氨化制环己胺反应中的应用。
The preparation methods of the Cu/ZrO2 catalyst are introduced. The effects of promoters on the physiochemical and catalytic properties of the Cu/ZrO2 catalyst are presented. The applications of the Cu/ZrO2 catalyst in the synthesis of methanol from hydrogenation of CO and/or CO2, production of hydrogen from steam reforming of alcohols, dehydrogenation of diethanolamine to diglycolamidic salt, dehydrogenation of cyclohexanol to cyclohexanone, and reductive amination of cyclohexanol to cyclohexylamine are summarized.
出处
《化工进展》
CAS
CSCD
北大核心
2008年第6期837-843,共7页
Chemical Industry and Engineering Progress
基金
上海市自然科学基金资助项目(06ZR14080)
上海市曙光计划项目(06SG35)
上海市重点学科建设基金资助项目(P1501)
关键词
铜
氧化锆
催化剂
甲醇合成
醇类制氢
copper
zirconia
catalyst
synthesis of methanol
production ofhydrogenfromalcohols
