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基于N-乙基咔唑-2-乙烯基-8-羟基喹啉锌的黄绿色有机电致发光器件的性能 被引量:9

Properties of Yellow-Green Organic Light-Emitting Devices Based on (E)-2-(2-(9-ethyl-9H-carbazol-3-yl)vinyl) Quinolato-Zinc
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摘要 通过用一种既具有空穴传输特性又具有发光特性的新型荧光染料N-乙基咔唑-2-乙烯基-8-羟基喹啉锌((E)-2-(2-(9-ethyl-9H-carbazol-3-yl)vinyl)quinolato-zinc,CzHQZn)作为受主,制备了结构为ITO/2T-NATA(30nm)/CBP:6%Ir(ppy)3∶wCzHQZn(20nm)/Alq3(50nm)/LiF/Al(ITO:indium-tinoxide,2T-NATA:4,4′,4′′-{N,N-(2-naphthyl)-N-phenylamino}-triphenylamine,CBP:4,4-N,N′-dicarbazole-biphenyl,Ir(ppy)3:factris(2-phenylpyridine)iridium,Alq3:tris(8-quinolinolato)aluminum;w是CzHQZn的质量分数)的黄绿色有机电致发光器件(OLEDs).研究了掺杂体系在不同掺杂浓度(w=5%、10%、12%、15%)时的电致发光(EL)特性.结果表明,CzHQZn掺杂浓度为10%的器件在11V电压下实现了黄绿光发射,色坐标为(0.4045,0.5113),最大发光亮度为16110cd·m-2;而在7V电压下的最大发光效率为2.19cd·A-1,最大外量子效率为0.775%. We investigated the performance of yellow-green organic light-emitting devices (OLEDs) based on a novel material (E)-2-(2-(9-ethyl-9H-carbazol-3-yl)vinyl) quinolato-zinc (CzHQZn) with an emitting/hole-transporting layer as an acceptor. These devices were fabricated as follows: ITO/2T-NATA(30 nm)/CBP: 6% Ir(ppy)3: w CzHQZn (20 nm)/Alq3(50 nm)/LiF/Al (ITO: indium-tin oxide, 2T-NATA: 4,4',4″-{N,N-(2-naphthyl)-N-phenylamino}- triphenylamine, CBP: 4, 4-N, N'-dicarbazole-biphenyl, Ir(ppy)3: factris (2-phenylpyridine) iridium, Alq3: tris(8-quinolinolato) aluminum; w: mass fraction of CzHQZn). After studying the electroluminescence (EL) characteristics of these devices at different doping concentrations (w=5%, 10%, 12%, 15%), yellow-green OLEDs with 10% of CzHQZn were obtained with Commission International de L'Eclairage coordinates of (0.4045, 0.5113). The maximum luminance was 16110 cd·m^-2 at an applied voltage of 11 V and the maximum luminous efficiency was 2.19 cd·A^-1 at an applied voltage of 7 V with a maximum external quantum efficiency of 0.775%.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2009年第5期958-962,共5页 Acta Physico-Chimica Sinica
基金 国家自然科学基金(20471020,20671036) 国家青年基金(10804036) 吉林省科技发展计划项目(20050523,20080528) 吉林省教育厅科研计划项目(吉教科合字[2003]第25号,吉教科合字[2004]第54号) 广东省科技项目(2006A10801002)资助
关键词 有机电致发光器件 锌金属配合物 掺杂 亮度 外量子效率 Organic light-emitting device (E)-2-(2-(9-ethyl-9H-carbazol-3-yl)vinyl) quinolato-zinc Doped Luminance External quantum efficiency
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