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光催化氧化法去除水中的酚类物质 被引量:5

Photo Oxidation of Phenols in Aqueous Suspension of Titanium Dioxide
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摘要 选取水中常见的酚类物质(如邻硝基酚、邻氨基酚和邻苯二酚)作为研究对象,在以TiO2(锐钛矿型)为催化剂、高压汞灯照射下研究其在水溶液中的降解情况。实验结果表明:酚类物质较易发生光催化降解。邻硝基酚、邻氨基酚和邻苯二酚的降解可近似看作一级反应,其半衰期分别为32.4,22.4,13.9min,并从反应机理上给予了解释。水中邻硝基酚的紫外吸光值随时间的变化情况的测定结果说明该物质在水中矿化较完全。 Photocatalytic oxidation of phenols in aqueous suspension was studied in this paper This compounds which were treated with UV illuminated titanium dioxide powder in aqueous suspension were easily degredated The degredation of phenols was investigated via first order kinetics and the half lives of 2 nitrophenol,2 aminophenol and catechol were 32 4, 22 4 and 13 9 min respectively Ultraviolet adsorbance of 2 nitrophenol was determined at 254nm and the mineralization was complete
出处 《山东建材学院学报》 1998年第2期107-108,114,共3页 Journal of Shandong Institute of Building Materials
关键词 光催化氧化 二氧化钛 酚类物质 废水处理 photocatalytic oxidation titanium dioxide phenols
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参考文献4

  • 1David F O, Ezio P, Nick S. Destruction of water coatamimats. Environ Sci Technol, 1991, 25 (9) : 1523-1528.
  • 2贺北平,王占生,张锡辉.半导体光催化氧化有机物的研究现状及发展趋势[J].环境科学,1994,15(3):80-83. 被引量:84
  • 3Barbeni M. Morello M: Pramauro E. et al. Sunlight photodegradation of 2, 4, 5-trichlorophenoxy-acetic acid and 2. 4, 5-trichlorophenol on TiO2.Chemosphere, 1987, 16(6) : 1165-1179.
  • 4Minero C, Pelizzetti E, Pichat P. et al, Formation of condensation products in advanced oxidation technologies:The photocatalytic degradation of dichlorophenols on TiO2. Environ ,Scien & Technol. 1995, 29 (8) :2226-2233.

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