摘要
以３，３二硝基氮杂环丁烷（ＤＮＡＺ）含能单体分别与光气及草酰氯反应，制得了两种多硝基化合物。经元素分析及红外、核磁共振光谱鉴定了它们的结构，并用ＤＳＣ法测定了它们的热分解的动力学参数。还用ＳＣＦＭＯＡＭ１方法对二（３，３二硝基氮杂环丁烷）酮进行了“量化”计算，求得了全优化几何构型和电子结构。
By condensation reaction of 3,3 dinitroazetidine with phosgene and oxalyl chloride,two polynitrocompounds were obtained. Their thermal kinetic parameters were determined by DSC experiment and structure were identified by IR spectrum,NMR analysis. Quantum chemistry calculation for bis(3′,3′ dinitroazetidine)one was made by using SCF MO AM1 code and the optimal geometric configuration and electronic structure were obtained therefrom.
出处
《含能材料》
EI
CAS
CSCD
1998年第2期73-77,共5页
Chinese Journal of Energetic Materials
关键词
二硝基
氮杂环丁烷
AMI方法
DSC
热分解
dinitroazetidine, AM1 method, condensation reaction, DSC, thermal decomposition.
