期刊文献+

β沸石的催化裂化反应性能 被引量:8

PROPERTIES AND CATALYTIC CRACKING PERFORMANCE OF β-ZEOLITES
在线阅读 下载PDF
导出
摘要 分别以催化汽油、直馏柴油、重油为原料,对硅/铝比(n(SiO2)/n(Al2O3))为14的β沸石和硅/铝比(n(SiO2)/n(Al2O3))为31的ZSM-5分子筛催化剂的催化裂化反应性能进行了对比评价。结果表明,β沸石对汽油组分的选择裂化能力弱于ZSM-5分子筛,而对柴油组分的裂化能力强于ZSM-5分子筛。β沸石作为助剂在催化裂化反应中有利于减少汽油损失、提高重油转化和轻油收率,也可起到增产丙烯、提高汽油辛烷值的作用。 Catalytic gasoline, straight-run diesel oil and heavy oil were used as stocks to evaluate the catalytic cracking properties of the β-zeolite with silica to alumina molar ratio of 14 and the ZSM-5 with silica to alumina molar ratio of 31. The results showed that the selective cracking capacity for gasoline of β-zeolite was weaker than that of ZSM-5, and its cracking capacity for diesel oil and heavy oil was stronger than that of ZSM-5. Therefore, with β-zeolite as the auxiliary catalyst the loss of gasoline could be reduced, the conversion of heavy oil could be enhanced and the yield of light oil could be increased, to increase the overall yields of propylene and to raise octane number of gasoline.
出处 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2009年第A02期77-79,共3页 Acta Petrolei Sinica(Petroleum Processing Section)
关键词 Β沸石 ZSM-5 催化裂化性能 beta zeolite ZSM-5 catalytic cracking properties
  • 相关文献

参考文献6

  • 1NEWSAM J M, M TREACY M J, KOETSIER W T,et al. Structural characterization of zeolite beta[J]. Proc Roy Soc Lond, 1988, A420: 375-405.
  • 2WANG H, XIN W. Surface acidity of h-Beta and its catalytic activity for alkylation of benzene with propylene [J]. Catalysis Letters, 2001, 76(3/4):225-229.
  • 3LANDAU M V, VRADMAN L, VALTCHEV V, et al. Hydrocracking of heavy vacuum gas oil with a Pt/H-beta-Al2O3 catalyst: Effect of zeolite crystal size in the nanoscale range[J].Ind Eng Chem Res, 2003, 42 (12):2773-2782.
  • 4SUB L, NORBERG V. Adsorption behavior of benzene in NaBeta zeolite: An in-situ infrared study of molecular recognition[J].Langmuir, 1998, 14 (26): 7410-7419.
  • 5SALINAS A L M, KONG D, TAARIT Y B, et al. Continuous iC (4)/C - 4 ( = ) alkylation under iC (4) supercritical conditions over K2.5 H0.5 PW12O40 and H- beta solid acids[J]. Ind Eng Chem Res, 2004, 43(20) : 6355-6362.
  • 6GOA Y, WU P, TATSUMI T. Catalytic performance of [Ti, Al]-beta in the alkene epoxidation controlled by the postsynthetic ion exchange[J].J Phys Chem B, 2004, 108(24): 8401-8411.

同被引文献52

引证文献8

二级引证文献21

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部