摘要
Polarization data of BH-4 oxidation on Cu anode in alkaline solution were measured at steady state by a self-made experimental cell.The experimental polarization curve showed three regions:the region at lower over-potential η(below 0.4 V approximately),the region at higher η(above 0.6 V approximately)and the transitional region at medium η.It was found that the limiting current density is caused by the limiting elemental step rather than the external mass transport.The apparent reaction order with respect to BH-4 changes from 0 to 1.The active energy is about 40 kJ·mol-1 in both regions with lower and higher η,and is higher than 40 kJ·mol-1 in the transitional region.With the experimental temperatures and NaOH concentration,the hydrogen production rates released by the electrode reaction were measured at [BH-4]/[OH-]ratios of 1:40,1:20,1:6.7 and 1:4,which is strongly dependent on the over-potential.The apparent number of released electron n by the reaction was calculated by using the measured amounts of hydrogen and coulomb.Higher value of n was obtained at lower [BH-4]/[OH-]ratio,higher temperature as well as higher over-potential.Under the experimental conditions,the value of n varies from 0 to 7,while in the transitional region it is just in the range of 3 to 5.The experimental results indicate that the limiting current density or n value will increase by virtue of proper experimental conditions.However,to considerably increase the current density at lower over-potential requires a modified anode with higher activity.
Polarization data of BH4^- oxidation on Cu anode in alkaline solution were measured at steady state by a self-made experimental cell. The experimental polarization curve showed three regions, the region at lower over-potential η （below 0. 4 V approximately）, the region at higher η （above 0.6 V approximately） and the transitional region at medium η. It was found that the limiting current density is caused by the limiting elemental step rather than the external mass transport. The apparent reaction order with respect to BH4 changes from 0 to 1. The active energy is about 40 kJ · mol^-1 in both regions with lower and higher η, and is higher than 40 kJ · mol^-1 in the transitional region. With the experimental temperatures and NaOH concentration, the hydrogen production rates released by the electrode reaction were measured at [BH4^-] /[OH^-] ratios of 1 ： 40, 1 ： 20, 1 ： 6.7 and 1 ： 4, which is strongly dependent on the over-potential. The apparent number of released electron n by the reaction was calculated by using the measured amounts of hydrogen and coulomb. Higher value of n was obtained at lower [BH4^- ] /[OH^-] ratio, higher temperature as well as higher over-potential. Under the experimental conditions, the value of n varies from 0 to 7, while in the transitional region it is just in the range of 3 to 5. The experimental results indicate that the limiting current density or n value will increase by virtue of proper experimental conditions. However, to considerably increase the current density at lower overpotential requires a modified anode with higher activity.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2009年第11期2862-2868,共7页
CIESC Journal
基金
国家自然科学基金项目(20776091)
高等学校博士学科点专项科研基金项目(200801120010)~~
