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几种尖晶石型复合氧化物纳米粉体的制备及气敏性 被引量:12

Preparation and Gas sensitivity of Several Spinel type Nanocrystalline Mixed Oxides
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摘要 采用化学共沉淀法合成了4种尖晶石型复合氧化物MFe2O4(M=Cu2+,Zn2+,Cd2+,Mg2+).X射线粉末衍射分析、透射电镜及比表面测定等表征结果表明它们均为具有较大比表面积的纳米粉体,平均粒径<50nm.将样品做成厚膜型气敏元件,测定了其对乙炔、液化石油气、一氧化碳、氢气和乙醇等还原(可燃)性气体的气敏特性. Four spinel type mixed oxide nanocrystalline powders MFe 2O 4(M=Cu 2+ , Zn 2+ , Cd 2+ and Mg 2+ ) were prepared by chemical coprecipitation method. The products were characterized by means of powder XRD, TEM and specific surface area measurements. The results reveal that the samples are nanocrystalline powders with high specific surface areas. Their gas sensitivities to reductive gases depend on their specific surface area: the larger the specific surface area, the higher the sensitivity.
出处 《应用化学》 CAS CSCD 北大核心 1998年第5期14-17,共4页 Chinese Journal of Applied Chemistry
关键词 气敏材料 尖晶石型 纳米晶 气敏性 复合氧化物 spinel type mixed ferric oxide,nanocrystalline,preparation,gas sensitivity
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