摘要
Yb^3+:Er^3+:Tm^3+co-doped borosilicate glasses are prepared. Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared, which are excited by a 978-nm laser diode, are measured, and the mechanisms of energy transfer among Yb^3+ Er^3+ and Tm^3+ ions are discussed. The results show that there is an unexpected wavelength at 900-nm emission from Yb^3+ Stark splitting levels to pump Tm^3+ ions and there exists an optimum pump power. The concentration of the Tm^3+ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the yb^3+:Er^3+:Tm^3+ co-doped borosilicate glasses.
Yb^3+:Er^3+:Tm^3+co-doped borosilicate glasses are prepared. Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared, which are excited by a 978-nm laser diode, are measured, and the mechanisms of energy transfer among Yb^3+ Er^3+ and Tm^3+ ions are discussed. The results show that there is an unexpected wavelength at 900-nm emission from Yb^3+ Stark splitting levels to pump Tm^3+ ions and there exists an optimum pump power. The concentration of the Tm^3+ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the yb^3+:Er^3+:Tm^3+ co-doped borosilicate glasses.
基金
Project supported by the National Natural Science Foundation of China (Grant No. 10804015)
the Science Foundation of the Education Department of Liaoning Province of China (Grant No. 2009A417)