摘要
以丁二酸酐、无水乙醇、氯化亚砜为原料合成丁二酸单乙酯酰氯。最佳工艺条件为：ｍ（丁二酸酐）∶ｍ（乙醇）∶ｍ（氯化亚砜）＝１∶０．５６∶１．６；酯化反应时间２ｈ，反应温度９０℃；酰氯化反应时间５ｈ，反应温度５５～６０℃。产品收率达８９％以上。
Ethyl succinyl chloride was synthesized with succinic anhydride,alcohol and thionyl chloride as raw materials. The optimum condition was : m (succinic anhydnide)∶ m (alcohol)∶ m (thionyl chloride)=1∶0.56∶1.6;esterification reaction time,2h;temperature,90℃;acidylation reaction time,5h;temperature,55～60℃. The yield was over 89%.
出处
《江苏化工》
1998年第6期22-23,共2页
Jiangsu Chemical Industry
