摘要
落叶松栲胶经过高度亚硫酸化反应,小分子部分增多,产物平均分子量降低,Na2SO3 和NaHSO3 总用量为30 % 时,分子量低于713 的组分由30 % 增加到60 % ,其分布变得更均匀,色度值、粘度值、盐析值均下降,耐酸性增强,用于制革时,渗透速率增加,具有比传统方法生产的栲胶更优良的结合鞣、复鞣及填充性能。
This research refers to comprehensive improvement of tanning properties of larch bark tannin extract.Intensive sulfitation was adopted so that the product has faster penetration into pelt and relatively moderate astringency,which is the requirement of modern leather making.Degradation of tannin was increased with the increase of sulfite dosage.When 30 % sulfite was used,the components with molecular weight lower than 710 increased to 60 % of the extract,doulbed in comparison with the original tannin extract.As a result the product having lower average molecular weight,reduced viscosity,lighter color and better salt out and acid endurable ability was obtained.Used in combination tannages,or as retanning agent,the performances of the modified product were obviously improved.
出处
《林产化学与工业》
EI
CAS
CSCD
北大核心
1999年第4期1-6,共6页
Chemistry and Industry of Forest Products
基金
国家自然科学基金
关键词
植物单宁
落叶松树
皮栲胶
硫酸化
皮革
胶粘剂
vegetable tannin
larch bark tannin extract
intensive sulfitation
leather chemicals