摘要
合成了具有柔性取代基的2(3),9(10),16(17),23(24)-四-(N,N-二乙胺基乙氧基)Cu-酞菁配合物,并且装载到MCM-41中。利用UV-Vis-Nir,FT-IR,XRD,TEM,FESEM及N2吸附-脱附等温线对制备的样品进行了表征。研究表明:制备的Cu-酞菁配合物能够装载到MCM-41中;较高浓度的Cu-酞菁配合物在MCM-41中的装载,有利于制备结晶度及孔道有序性较高的介孔分子筛样品。
The 2（3）,9（10）,16（17）,23（24）-tetra-（N,N-bisethylamineethoxyl） Cu（Ⅱ）-phthalocyanine complexes with flexible peripheral substituents were synthesized and encapsulated in mesoporous molecular sieves MCM-41.The prepared samples were characterized by UV-vis-Nir,FT-IR,XRD,TEM,FESEM and N2 adsorption-desoption isotherms.Results show that the prepared phothalocyanine copper（Ⅱ） was encapsulated in mesoporous molecular sieves MCM-41 in the form of monomer and dimer.The phothalocyanine copper（Ⅱ） encapsulated in MCM-41 with high concentration was in favour of preparing mesoporous molecular sieves samples with higher crystallinity and pore channel order.
出处
《太原理工大学学报》
CAS
北大核心
2011年第5期470-474,共5页
Journal of Taiyuan University of Technology
基金
国家自然科学基金资助项目(20472014)
