摘要
介绍了近年来铑／膦催化高碳烯烃氢甲酰化的研究和开发进展，特别是以 ＴＰＰＯ／Ｒｈ为催化剂的 Ｍｉｔｓｕｂｉｓｈｉ Ｋａｓｅｉ工艺和水／有机两相体系为主的各种两相催化技术。近年的进展表明，通过创新膦配体以及采用两相催化体系，有望使更有效、更经济的铑催化工艺在高碳烯烃氢甲酰化的应用中取得突破。
The studies on the hydroformylation of higher olefins over rhodium-phosphine catalysts in the past decade were reviewed. In this paper, we introduced the process in Mitsubishi Kasei over TPPO/Rh and the developments in biphasic catalysis in this field, especially the water-organic two-phase catalysis. These studies show there will be a more effective rhodium catalysis technology to expedite the application of the hydroformylation of higher olefins by developing novel phosphine ligands and adopting two-Phase catalysis systems in the near future.
出处
《化工进展》
EI
CAS
CSCD
2000年第1期28-31,共4页
Chemical Industry and Engineering Progress
关键词
高碳烯烃
氢甲酰化
铑
膦
催化剂
高碳醇
催化
higher olefins, hydroformylation, rhodium-phosphine catalyst, higher alcohol, two-phase catalysis
