期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

新型二维全无机的多酸化合物Na_(13)H_5[Pr(W_5O_(18))_2]_2·62H_2O的合成、晶体结构和荧光性质 被引量：2

A new 2D All-inorganic Polyoxometalate Na_(13)H_5[Pr(W_5O_(18))_2]_2·62H_2O:Synthesis,Crystal Structure and Luminescent properties
在线阅读 下载PDF
导出
摘要 在pH值约为6.5的水溶液中,K12[Sb2W22O74(OH)2]·27H2O,PrCl3.7H2O和Na2CO3的反应得到了一个基于[Pr(W5O18)2]9-阴离子和Na+的新型二维全无机的多酸化合物Na13H5[Pr(W5O18)2]2·62H2O.通过单晶X射线衍射、红外光谱、紫外光谱和元素分析对标题化合物的结构进行了表征,并且对标题化合物的荧光性质进行了测试. A new 2D all-inorganic polyoxometalate compound Na13H5[Pr（W5O18）2]2·62H2O based on the [Pr（W5O18）2]9-anions and Na＋ ions was synthesized by the reaction of K12[Sb2W22O74（OH）2]·27H2O,PrCl3·7H2O and Na2CO3 in aqueous solution at a pH value of about 6.5.The obtained compound is characterized by single-crystal X-ray diffraction,IR spectrum,UV spectrum and elemental analysis.The luminescent properties of the compound were characterized.
作者 崔克宇 葛玲玉
机构地区 吉林师范大学化学学院
出处 《吉林师范大学学报（自然科学版）》 2012年第2期32-35,40,共5页 Journal of Jilin Normal University:Natural Science Edition
基金 四平市科技局项目(2009013)
关键词 多酸 全无机 荧光 polyoxometalate all-inorganic luminescent
分类号 O611.4 [理学—无机化学]
  • 相关文献

参考文献13

  • 1Proust, A. , Thouvenot, R. , Gouzerh, P.. Functionalization of polyoxometalates : towards advanced applications in catalysis and materials science [ J]. Chem. Commun. 2008 : 1837 ~ 1852.
  • 2Long,D. L. ,Tsunashima, R. , Cronin, L. Polyoxometalates: Building Blocks for Functional Nanoscale Systems [ J]. Angew. Chem. Int. Ed. 2010, 49 : 1736 ~ 1758.
  • 3Kuang, X. J. , R. Evans, I. Four New Dysprosium and Neodymium Octamolybdate Hydrates:Assembly of RE2 (Mos 027 ) Sheets and Topotactic Transformations[ J]. Inorg. Chem. 2010,49:6005 ~ 6012.
  • 4Khan,M. I. ,Yohannes,E. ,Doedens,R. J. [M3VlsO42(H20)la(XO4) ] ~ 24H20(M = Fe,Co;X = V,S) :Metal Oxide Based Framework Ma- terials Composed of Polyoxovanadate Clusters [ J ]. Angew. Chem. Int. Ed. 1999,38 : 1292 ~ 1294.
  • 5Zhang, X. T. , et al. Polyoxometalate (W/Mo) Compounds Connected via Lanthanide Cations with a Three-Dimensional Framework, H2 {[ K (H20) 2 ] 2 [ Ln( H2 O) 5 ] 2 ( H2M12 042 ) t " nH20 : Synthesis, Structures,and Magnetic Properties[ J]. Inorg. Chem. 2006,45 : 10629 ~ 10635.
  • 6Liu, H. Y. , et al. Inorganic-organic hybrid compounds based on octamolybdates and metal-organic fragments with ? exible multidentate ligand : syn- theses, structures and characterization [ J ]. Dalton Trans. 2011,40 : 602 ~ 613.
  • 7Zang, H. Y. , et al. Step-wise synthesis of inorganic-organic hybrid based on 3,-octamolybdate-based teetons [ J ]. Dalton Trans. 2011,40:3176 ~ 3182.
  • 8Bcsing, M. , et al. New Strategies for the Generation of Large Heteropolymetalate Clusters:The 13-B-SbW9 Fragment as a Muhifunctional Unit [ J ]. Chem. Eur. J. 1997,8 : 1232 ~ 1237.
  • 9W. L. Chan, et al. Building block approach to nanostructures : step-by-step assembly of large lanthanide-containing polytungstoarscnate aggregates [ J]. Dalton Trans. 2007:4293 ~ 4301.
  • 10H. Liu,et al. Copper-Complex-Linked Polytungsto-Bismuthate(-Antimonite) Chain Containing Sandwich Cu(II) Ions Partially Modified with Im- idazole Ligand[J]. Inorg. Chem. 2008,47:4166 ~ 4172.

同被引文献22

引证文献2

二级引证文献1

吉林师范大学学报（自然科学版）
2012年 第2期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部