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Fe3O4/C的制备与电化学性能研究 被引量:1

Electrochemical Performance of Fe_3O_4/C Composites as Negative Material for Lithium-Ion Batteries
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摘要 应用共沉淀法并以原位聚合苯胺包覆Fe3O4作碳源制备Fe3O4/C的复合材料.XRD、SEM、TEM等测试显示,样品中Fe3O4纳米颗粒(40~80 nm)均匀分散在无定形碳的内部.在50 mA.g-1电流密度下,经过30次循环充放电测试,该材料的容量仍保持在1000 mAh.g-1左右. The Fe3O4/Carbon composites have been synthesized through coprecipitation pathway and by insitu aniline polymerization as a carbon source. Structural characterization and morphological study of the composites were investigated by using XRD, SEM and TEM techniques. The results showed that the nanosized Fe3O4 particles(40 - 80 nm) were encapsulated in the amorphous carbon. During the electrochemical tests, the Fe3O4/C composites exhibited high capaticity and excellent cycle ability, the retention of capaticity was about 1000 mAh·g^-1 after 30 cycles of charge/discharge tests at 50 mA·g^-1
出处 《电化学》 CAS CSCD 北大核心 2013年第1期89-92,共4页 Journal of Electrochemistry
基金 国家自然科学基金(No.21073241,No.U1034003)资助
关键词 FE3O4 负极材料 锂离子电池 无定形碳 Fe3O4 negative materials Li-ion batteries amorphous carbon
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