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Sol-Gel法制备Bi_2O_3·3MoO_3复合氧化物催化剂及其表面酸碱性的微量吸附量热研究

Preparation of Bi_2O_3·3MoO_3 Oxide Catalyst by Sol Gel Method and its Microcalorimetric Studies of Surface Acidity and Basicity
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摘要 Bi2O3· 3MoO3 oxide catalyst has been prepared by the sol gel pr℃ ess at lower temperature. The influences of preparation conditions and thermal treatment conditions on the morphology and structure of the catalyst have been studied by using TEM, DTA TG, FT IR, XRD and BET surface area measurement methods. It is shown that the BET surface area of Bi2O3· 3MoO3 prepared by sol gel method is larger than that of Bi2O3· 3MoO3 prepared by coprecipitation method. For the preparation of the well distribuated Bi2O3· 3MoO3 catalyst has a BET surface area of 13.2m2· g- 1, the optimum conditions for the catalyst are : Bi2O3· 3MoO3 oxide catalyst has been prepared by the sol gel pr℃ ess at lower temperature. The influences of preparation conditions and thermal treatment conditions on the morphology and structure of the catalyst have been studied by using TEM, DTA TG, FT IR, XRD and BET surface area measurement methods. It is shown that the BET surface area of Bi2O3· 3MoO3 prepared by sol gel method is larger than that of Bi2O3· 3MoO3 prepared by coprecipitation method. For the preparation of the well distribuated Bi2O3· 3MoO3 catalyst has a BET surface area of 13.2m2· g- 1, the optimum conditions for the catalyst are : pH
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2000年第4期675-679,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金!( No.29973013) 国家重点基础研究发展规划项目!(G1999022408) 南京大学现代分析中心测试基金
关键词 复合氧化物催化剂 SOL-GEL法 氧化铋 氧化钼 Bi_2O_3.3MoO_3 oxide catalyst sol-gel method microcalorimetric adsorption
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二级参考文献3

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  • 2Shen J Y,Langumuir,1994年,10卷,3902页
  • 3Rao C N R,J Phys Chem,1992年,96卷,18期,7379页

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