摘要
发现一种磺酰氯和叔胺反应生成N,N-二取代磺酰胺的反应类型,以1,3-二磺酰氯-4,6-二烷氧基苯和2,4,6-三(二甲氨基甲基)苯酚为原料,二氯甲烷或丙酮作溶剂,合成了4个芳磺酰胺类化合物。通过IR、1H NMR、元素分析和MS谱对其组成结构进行了表征。测试了它们对Ca2+、Pb2+及部分过渡金属等10种金属离子的萃取性能。结果表明,此类化合物对Ca2+有良好的选择性识别作用。
N,N-disubstituted sulfonamide between sulfonyl chlorides and tertiary amines was discovered.Four aromatic sulfonamides were synthesized in dichloromethane or acetone by using 4,6-dialkoxy-benzene-1,3-disulfonyl dichlorides and 2,4,6-tris（dimethylaminomethyl）phenol as the starting materials.The purified products were characterized by IR,1H NMR,elemental analysis and MS.Aromatic sulfonamides were then applied as the extraction reagents for Ca2＋,Pb2＋ and some transition metal cations.The primary results showed that the aromatic sulfonamides have better extraction capability for Ca2＋.
出处
《应用化学》
CAS
CSCD
北大核心
2013年第4期427-430,共4页
Chinese Journal of Applied Chemistry
基金
湖南省重点学科建设项目资助
湖南省教育厅科研项目(11C0376)
衡阳市科学技术局科技计划项目(2010KS42)
湖南工学院科学研究项目(HY10009
HY09016)
关键词
合成
选择性萃取
二烷氧基苯二磺酰二烷基胺
磺酰胺
synthesis
selective extraction
dialkoxybenzene disulfonic acid bis-dialkylamide
sulfonamide
