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微生物异化还原及其对硝基苯的耦合降解 被引量:3

Coupled Degradation of Nitrobenzene by Bacterial Dissimilatory Iron Reduction
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摘要 通过静态实验对地下环境中微生物异化还原降解硝基苯作用及其影响因素进行了研究。结果表明,铁还原微生物能以简单有机物为碳源生长并还原针铁矿,硝基苯可以作为唯一碳源被铁还原微生物利用。随着硝基苯浓度的升高,铁还原微生物的生长逐渐受到抑制。硝基苯浓度为600 mg/L时,铁还原微生物的生长停滞。针铁矿浓度0.3 mg/L、铁还原微生物浓度2×108cells/mL时耦合体系对硝基苯降解效果最好,硝基苯降解率达78.5%以上。腐植酸能作为电子穿梭体促进耦合体系中硝基苯的衰减,硝基苯降解率达88.8%以上,而维生素B2(VB2)抑制了硝基苯的降解。 Static experiments were designed to investigate the process and influencing factors of nitrobenzene degradation coupled to bacterial dissimilatory iron reduction in sub-surface environment. The result indicated that iron reducing bacterial could utilize simple organics as electron donor to reduce goethite. With the rise of the concentration of nitrobenzene which could be used as the sole electron donor, the growth of bacterial was restrained gradually and stopped while its concentration over 600 mg/L. The highest removal efficiency ot nltrobenzene was observed at 0. 3 mg/L goethite and 2 x 10s Cells/mL microbial biomass system, and the degradation rate of nitrobenzene was over 78.5%. Electron shuttle, humic acid, could enhance the attenuation of nitrobenzene, and its degradation rate was up to 88.8%. However, VB2 inhibites the degradation of nitrobenzene.
出处 《科学技术与工程》 北大核心 2013年第24期7121-7125,共5页 Science Technology and Engineering
关键词 异化还原 针铁矿 硝基苯 电子穿梭体 dissimilatory reduction goethite nitrobenzene electron shuttles
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参考文献15

  • 1Haderlein S B, Pecher K. Pollutant reduction in heterogeneous Fe (II)/Fe (III) systems. In : kinetics and mechanisms of reactions at the mineral/water interface, ACS symposium series, division of geo- chemistry:Sparks D L, Grundl T, Eds. ; American Chemical Socie-ty: Washington, DC, 1998, 715(17):342-357.
  • 2Sanggoo K, Flynn W P. Enhanced anaerobic biotransformation of car- bon tetrachloride in the presence of reduced iron oxides. Env Toxicol Chem, 1999 ; 18 (10) : 2142-2150.
  • 3Joerg K, Serge P T, Stefan B H, et al. Reduction of substituted ni- trobenzenes by Fe (II) in aqueous mineral suspensions. Env Sci Technol, 1995 ;29 ( 9 ) : 2396-2404.
  • 4许超,董军,马小兰,牛波,娄权正.微生物异化还原铁氧化物体系对硝基苯的降解作用[J].中国环境科学,2011,31(9):1472-1476. 被引量:11
  • 5David E C, Frank C Jr, Scott F, et al. Arsenic mobilization by the dissimilatory Fe(III)-reducing bacterium shewanella alga BrY. En- viron Sci Technol, 1999 ; 33 (5) : 723-729.
  • 6Heiko W L, William P I. Microbial reduction of arsenate in the pres- ence of ferrihydrite. Env Sci Technol, 2000;34 (15) : 3131-3136.
  • 7Scott E F, Li Guangchao. Kinetics of chromate reduction by ferrous i- ron. Env Sci Tech, 1996; 30(5) :1614-1617.
  • 8Cervantes F J, Duong-Dac T, Ivanova A E, et al. Selective enrich- ment of geobaeter sulfurredueens from anaerobic granular sludge with quinones as terminal electron aeeeptors. Biotechnology Letters, 2003 ; 25:39-45.
  • 9Anderson R T, Lovley D R. Hexadecane decay by methanogenesis. Nature, 2000 ; 404:722-723.
  • 10Jeon B H, Dempsey B A, Burgos W D. Kinetics and mechanisms for reactions of Fe( Ⅱ ) with iron( Ⅲ ) oxides. Environ Sci Technol, 2003 ;37 ( 15 ) :3309-3315.

二级参考文献34

  • 1吴双桃,陈少瑾,胡劲召,谢凝子,陈宜菲.零价铁对土壤中硝基苯类化合物的还原作用[J].中国环境科学,2005,25(2):188-191. 被引量:27
  • 2曲东,贺江舟,孙丽蓉.不同水稻土中氧化铁的微生物还原特征[J].西北农林科技大学学报(自然科学版),2005,33(4):97-101. 被引量:28
  • 3Connor O A O, Young L Y. Toxicity and anaerobic biodeg radability of substituted phenols under methanoganic conditions [J]. Environmental Toxicology and Chemistry, 1989,8(10):853- 862.
  • 4Agrawal A, Tratnyek P G.Reduction of nitro aromatic compounds by zerovalent iron metal [J]. Environ Sei. Technol., 1996,30(1): 153-160.
  • 5Anderson R T, Lovley D R. Hexadecane decay by ethanogenesis [J]. Nature, 2000,404:722-723.
  • 6Klansen J, Trober S P, Haderlein S B, et at. Reduction of substituted nitrobenzenes by Fe( II ) in aqueous mineral suspensions [J]. Environ. Sci. Technol., 1995,29(9):2396-2404.
  • 7Erbs M, Hansen H C B,Olsen C E. Reductive dechlorination of carbon tetrachloride using iron(II) iron(III) hydroxide sulfate (Green Rust) [J]. Environ. Sci. Technol, 1993,33:307-311.
  • 8Hwang I, Batchelor B. Reductive dechlorination of tetrachloro ethylene by Fe(II) in cement slurries [J]. Environ. Sci. Technol., 2000,34:5017-5022.
  • 9Klaus P, Stefan B H, Rene P S. Reduction of polyhalogenated methanes by surface-bound Fe(II) in aqueous suspensions of iron oxides [J]. Environ. Sci. Technol., 2002,36:1734-1741.
  • 10Cornel R M I, Shwertmann U. Iron oxides in the laboratory. Preparation and characterization [M]. New York: VCH, Weinheim, 1991:60-80.

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