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一种绿色简便制备富勒醇的方法

A Simple and Green Method of Preparing Fullerenol
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摘要 为了解决富勒烯在水中溶解性差的问题,该文以富勒烯多氧化物为原料,在50℃下,将富勒烯多氧化物置于H2O2中水解,H2O2可以将富勒烯多氧化物进行二次氧化,成功制备了富勒醇。产品在水中溶解度可达59.8g/L。通过FTIR、UV-Vis、MALDI-TOF对产品进行了表征和分析。该文提供了一种制备富勒醇的简便方法,为其制备提供了借鉴。 In order to solve the problem of the poor solubility of fullerene in water, a method of preparing water-soluble fullerenol has been realized based on the fullerene oxides in this paper. In detail, the fullerene oxides were further oxidized and hydrolyzed by H202 to form more hydroxyl groups on fullerene cage under 50 ℃ to successfully synthesize fullerenol. The solubility of fullerenol is 59. 8 g/L. The target product was characterized by FTIR, UV-Vis and MALDI-TOF. Such a novel method of preparing fullerenol provides a new reference for the preparation methods of fullerenol. Key words：
作者 陈曲 蒋礼 葛春华 王春儒
机构地区 中昊(大连)化工研究设计院有限公司 中国科学院化学研究所 辽宁大学
出处 《精细化工》 EI CAS CSCD 北大核心 2014年第1期129-131,共3页 Fine Chemicals
关键词 富勒醇 富勒烯多氧化物 高水溶性 精细化工中间体 fullerenol fullerene oxides highly water-soluble fine chemical intermediates
分类号 TQ223.142 [化学工程—有机化工]
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参考文献11

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精细化工
2014年 第1期

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