纸包装油墨中增塑剂向奶粉的迁移被引量：10

Migration of Plasticizers from Paper Packaging Inks to Milk Powder

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摘要纸包装油墨中含有有毒有害物质并可通过包装材料迁移进入内装食品从而危害人体健康。模拟实际印刷条件制作真实油墨迁移单元，研究纸张胶印油墨中4种主要增塑剂（3种邻苯二甲酸酯类增塑剂和近年流行的环保增塑剂乙酰基柠檬酸三丁酯）向奶粉的迁移，考察其在100、70、50、25 ℃的迁移行为，探讨增塑剂的性质及其在纸张中的分布等因素对迁移行为的影响。结果表明：4种增塑剂的最大迁移率在6.7%～67.8%之间。纸包装油墨中增塑剂的迁移防护性能还有待提高。 The safe use of printing materials for food packaging is a major area of investigation. The hazardous substanceslike plasticizers in printing inks can migrate into the food through the packaging material. However, there have beenfew studies reporting the migration kinetics of the the plasticizers to food from ink. In this study, a novel method wasdeveloped for the study of migration of plasticizers from the printing inks through paper to milk powder at 100, 70, 50 ℃ and 25 ℃,respectively and for different contact times ranging from 5 min at 100 ℃ to 40 days at 25 ℃. The inks were offset printed bysimulating the real situation, hadwhich has never been used in migration research. The plasticizers investigated included thecommonly used dibutyl phthalate （DBP）, bis（2-ethylhexyl） phthalate （DEHP）, di-n-octyl phthalate （DOP） and a new type of theenvironmentally-friendly plasticizer, acetyl tributyl citrate （ATBC）. Gas chromatography coupled with ？ame ionization detector（GC-FID） was used for the determination of ethanol extracts of these plasticizers from both printed paper and milk powder. Theresults showed that the paper did not provide an appropriate barrier against the migration of the plasticizers from printing inks. Themaximum migration of DBP and ATBC reached almost 67.8% while that of DEHP and DOP was about 6.7%. The contact time,the temperature and the properties of the compounds are the factors affecting the real mass transfer.

作者高松王志伟胡长鹰吴宇梅

机构地区江南大学机械工程学院产品包装与物流广东普通高校重点实验室暨南大学包装工程研究所暨南大学食品科学与工程系

出处《食品科学》 EI CAS CSCD 北大核心 2014年第1期18-22,共5页 Food Science

基金国家自然科学基金项目(21077045 21277061) "十一五"国家科技支撑计划项目(2009BADB9B04-01) 中央高校基本科研业务费专项(21611360 21611460)

关键词油墨增塑剂纸包装迁移奶粉 inks plasticizers paper packaging migration milk powder

分类号 TQ021.4 [化学工程] TS206.4 [轻工技术与工程—食品科学]

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参考文献26

1ARVANITOYANNIS I S,BOSNEA L. Migration of substances from food packaging materials to foods[J].{H}Critical Reviews in Food Science and Nutrition,2004,(2):63-76.
2FRANZ R. Migration modelling from food-contact plastics into foodstuffs as a new tool for consumer exposure estimation[J].{H}Food Additives and Contaminants,2005,(10):920-937.
3WANG Zhiwei,WU Yumei,HU Changying. Packaging regulation and migration investigation in China[J].{H}ITALIAN JOURNAL OF FOOD SCIENCE,2012,(4):147-153.
4PO(C)AS M F,OLIVEIRA J C,PEREIRA J R. Consumer exposure to phthalates from paper packaging:an integrated approach[J].Food Additives and Contaminants Part A-Chemistry Analysis Control Exposure & Risk Assessment,2010,(10):1451-1459.
5CASTLE L,OFFEN C P,BAXTER M J. Migration studies from paper and board food packaging materials,1.Compositional analysis[J].{H}Food Additives and Contaminants,1997,(1):35-44.
6AURELA B,KULMALA H,SODERHJELM L. Phthalates in paper and board packaging and their migration into Tenax and sugar[J].{H}Food Additives and Contaminants,1999,(12):571-577.
7RICHTER T,GUDE T,SIMAT T. Migration of novel offset printing inks from cardboard packaging into food[J].Food Additives and Contaminants Part A-Chemistry Analysis Control Exposure & Risk Assessment,2009,(12):1574-1580.
8黄秀玲,王志伟.PE淋膜纸中UV墨光引发剂向食品模拟物的迁移行为[J].高分子材料科学与工程,2009,25(7):97-100. 被引量：11
9KOIVIKKO R,PASTORELLI S,RODRIGUEZ-BERNALDO de QUIROS A. Rapid multi-analyte quantification of benzophenone,4-methylbenzophenone and related derivatives from paperboard food packaging[J].Food Additives and Contaminants Part a-Chemistry Analysis Control Exposure & Risk Assessment,2010,(10):1478-1486.
10TRIANTAFYLLOU V I,AKRIDA-DEMERTZI K,DEMERTZIS P G. A study on the migration of organic pollutants from recycled paperboard packaging materials to solid food matrices[J].{H}Food Chemistry,2007,(4):1759-1768.