期刊文献+

EG协同三嗪系大分子膨胀型阻燃剂阻燃HDPE研究 被引量:1

Study on the Flame Retarding of HDPE by Synergetic Flame Retardance between EG and Triazine Macromolecular Intumescent Flame Retardant
原文传递
导出
摘要 研究了EG协同三嗪系大分子膨胀型阻燃剂阻燃HDPE,通过极限氧指数(LOI)、热重分析(TGA)、扫描电镜(SEM)等测试手段进行了分析。结果表明当EG与APP/CFA/SiO2共同使用阻燃HDPE的氧指数比单独加入两种阻燃剂的氧指数都有所提高,SEM测试表明EG与APP/CFA/SiO2共同使用燃烧后表面形成一层致密的保护层,阻止了聚合物的进一步燃烧。 The flame retarding of HDPE by synergetic flame retardance between EG and triazine macromolecular expansion flame retardant was studied. By means of the limiting oxygen index (LOI), thermal gravimetric analysis (TGA) and scanning electron microscope (SEM) tests, etc, the analysis was carried out. The research results showed that the LOI of flame-retardant HDPE with EG and APP/CFA/SiO2 was better than the LOI that the two kinds of flame retardants used alone. The SEM test indicated that there was a compact protective layer formed on the surface after combustion when EG and APP/CFA/SiO2 were used synergistically, which prevented further combustion of the polymer.
机构地区 东北林业大学
出处 《化学与粘合》 CAS 2014年第3期191-193,206,共4页 Chemistry and Adhesion
关键词 高密度聚乙烯 膨胀阻燃 可膨胀石墨 HDPE intumescent flame retardant expandable graphite
  • 相关文献

参考文献7

  • 1DASARI A, YU Z Z, MAI YW , et al. Roles of graphite oxide , clay and POSS during the combustion of polyamide 6 [J] . Polymer ,2009,50 (6) :1577.
  • 2SERGE B , MICHEL L B , SOPHIE D , et al. Recent advances for intumescent polymers [J] . Macromol Mater Eng ,2004,289 : 499.
  • 3田春明,谢吉星,王海雷,郭花枝,徐建中.膨胀石墨在聚乙烯中阻燃协效作用的研究[J].中国塑料,2003,17(12):49-52. 被引量:19
  • 4韩志东,吴泽,单连伟,马成国,张显友.膨胀阻燃聚乙烯的研究[J].中国塑料,2012,26(2):50-54. 被引量:5
  • 5LI B, XU M J . Effect of a novel charring- foaming agent on flame retardancy and thermal degradation of intumescent flame retardant polypropylene [J] . Polym. Degrad. Stab. , 2006, 91: 1380-1386.
  • 6LI Y T, LI B, DAI J F, et al . Synergistic effects of lanthanum oxideon a novel intumescent flame retardant polypropylene system [J] .Polym. Degrad. Stab. , 2008, 93: 9-16.
  • 7李艳涛,李斌,戴进峰.分子筛和SiO2对含三嗪大分子膨胀阻燃聚丙烯体系的阻燃协效性[J].高分子材料科学与工程,2009,25(6):56-59. 被引量:14

二级参考文献26

  • 1ZHANG S, HORROCKS A R. A review of flame retardant polypropylenefiber[J]. Prog. Polym. Sci., 2003, 28: 1517- 1538.
  • 2LI B, XU M J. Effect of a novel charring-foaming agent on flame retardancy and thermal degradation of intumescent flame retardant polypropylene[J]. Polym. Degrad. Stab., 2006, 91: 1380-1386.
  • 3LI Y T, LI B, DAI J F, et al. Synergistic effects of lanthanum oxide on a novel intumescent flame retardant polypropylene system [J]. Polym. Degrad. Stab., 2008, 93: 9-16.
  • 4BOURBIGOT S, BRAS M L, DELOBEL R, et al. Zeolite synergistic agent in new flame retardant intumescent formulations of polyethelenic polymers[J]. Polym. Dagrad. Stab., 1996, 54: 275-287.
  • 5王永强.阻燃技术[M].北京:化学工业出版社,2003:1-10.
  • 6Murphy J. Flame Retardants: Trends and New Developments [J]. Plastics Additives&Compounding, 2001, (4) : 16-20.
  • 7Levchik S V, Wild E D. Flame Retardancy of Thermoplastic Polyesters--A Review of the Recent Literature [J].Polym Int, 2005, 54(1): 11-35.
  • 8Gandi D. Flame Retardants: Some New Developments[J]. Plastics Additives and Compounding, 2001, (2): 1-3.
  • 9Baillet C, Gandi S. Fire Retardants of Polyethylene: Study of a Formulation Involving Phosphorous and Polyol Systems [J]. Polym Degrad Stab, 1992, 35: 149-158.
  • 10Kandola B K, Horrocks A R. Complex Char Formation in Flame Retarded Fibre-intumescent Combinations II. Thermal Analytical Studies[J]. Polym Degrad Stab, 1996, 54(2/3: 289-303.

共引文献35

同被引文献11

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部